Thexylborane

Base Information

• Chemical Name: Thexylborane
• CAS No.: 3688-24-2
• Molecular Formula: C6H15B
• Molecular Weight: 97.9961
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID401337129
• Wikipedia: Thexylborane
• Mol file: 3688-24-2.mol

Synonyms:thexylborane;(1,1,2-trimethylpropyl)borane;(2,3-Dimethyl-2-butanyl)borane;DFZFZKDSPYJVRQ-UHFFFAOYSA-N;DTXSID401337129;30001-14-0

Chemical Property of Thexylborane

Chemical Property:

• PSA: 0.00000
• LogP: 1.47400
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 96.1110306
• Heavy Atom Count: 7
• Complexity: 55.2

Purity/Quality:

THEXYLBORANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [B]C(C)(C)C(C)C

Technology Process of Thexylborane

There total 8 articles about Thexylborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3-Dimethyl-2-butene (563-79-1) + borane-THF (14044-65-6) → Thexylboran (3688-24-2)

Guidance literature:

In tetrahydrofuran; at 0 ℃; for 1h;

Reference yield:

2,3-Dimethyl-2-butene (563-79-1) + diborane (19287-45-7) → Thexylboran (3688-24-2)

Guidance literature:

In tetrahydrofuran; at 0 - 20 ℃; for 1.25h; Inert atmosphere;

DOI:10.1055/s-0036-1591488

Reference yield:

2,3-Dimethyl-2-butene (563-79-1) → Thexylboran (3688-24-2)

Guidance literature:

With dimethylsulfide borane complex; In toluene; at 0 ℃; Mechanism; Rate constant; time for the first 50percent of the reaction; effect of addition of SMe₂;

DOI:10.1021/ja00318a066

upstream raw materials:

2,3-Dimethyl-2-butene

dimethyl sulfide borane

dimethylsulfide borane complex

pyridine thexylborane

Downstream raw materials:

2,2'-(methyl(phenyl)silanediyl)bis(ethan-1-ol)