Carbonylbis(triphenylphosphine)rhodium(I) Chloride

Base Information

• Chemical Name: Carbonylbis(triphenylphosphine)rhodium(I) Chloride
• CAS No.: 13938-94-8
• Molecular Formula: C37H30ClOP2Rh
• Molecular Weight: 690.951
• Hs Code.: 28439090
• European Community (EC) Number: 237-712-8
• Mol file: 13938-94-8.mol

Synonyms:Carbonylbis(triphenylphosphine)rhodium(I) Chloride;13938-94-8;formaldehyde;rhodium;triphenylphosphane;chloride;C37H30ClOP2Rh;C37-H30-Cl-O-P2-Rh;EINECS 237-712-8;Carbonylchlorobis(triphenylphosphine)rhodium;Rhodium, carbonylchlorobis(triphenylphosphine)-;MFCD00044273;AKOS025402107;AC-4991

Chemical Property of Carbonylbis(triphenylphosphine)rhodium(I) Chloride

Chemical Property:

• Appearance/Colour: yellow crystals
• Melting Point: 224-227 °C (dec.)(lit.)
• PSA: 27.18000
• LogP: 6.92660
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility.: Soluble in acetone, chloroform, ethanol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 692.06719
• Heavy Atom Count: 42
• Complexity: 204

Purity/Quality:

99% ^*data from raw suppliers

Carbonylbis(triphenylphosphine)rhodium(I) Chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn, T
• Hazard Codes: Xn,T
• Statements: 20/21/22
• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Organic Compounds, Metal Salts
• Canonical SMILES: C=O.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
• Uses: Used for cyclometallation.

Technology Process of Carbonylbis(triphenylphosphine)rhodium(I) Chloride

There total 229 articles about Carbonylbis(triphenylphosphine)rhodium(I) Chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

5-hydroxymethyl-2-furfuraldehyde (67-47-0) + Wilkinson's catalyst (14694-95-2) → (2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + chlorocarbonylbis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8)

Guidance literature:

In further solvent(s); argon-filled glovebox, durene, bibenzyl, heating 24h at 70°C; detn. of products by GC;

DOI:10.1021/om00113a029

Reference yield: 94.0%

Wilkinson's catalyst (14694-95-2) + sorbose (57-48-7,87-79-6,87-81-0,551-68-8,3615-39-2,3615-56-3,6035-50-3,7776-48-9,16354-64-6,17598-81-1,17598-82-2,23140-52-5,30237-26-4,65732-90-3,73952-10-0,73952-11-1,139686-85-4,18875-34-8) → (2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + chlorocarbonylbis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8) + XYLITOL (87-99-0) + DL-1-deoxy-threitol (4144-94-9,4435-50-1,33818-52-9,41167-49-1,61913-75-5,61913-76-6,122920-28-9,138257-33-7)

Guidance literature:

In further solvent(s); argon-filled glovebox, durene, bibenzyl, heating 6h;

DOI:10.1021/om00113a029

Reference yield: 92.0%

Wilkinson's catalyst (14694-95-2) + Cinnamoyl chloride (102-92-1,17082-09-6) → chlorocarbonylbis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8)

Guidance literature:

With 1-hexene; In 1,2-dichloro-ethane; byproducts: styryltriphenyltriphosphonium chloride; evacuated and N2 added two times; dichloroethane addn.; evacuated untilboiled at room temp., and N2 added rapidly; cycle repeated; cooled to -78°C, tube sealed; heated 85°C 24 h; decane added; distd. the volatiles; residue recrysd. from dichloroethane;

DOI:10.1021/ja00396a031

upstream raw materials:

4-methylphenylacetaldehyde

tris(triphenylphosphine)chlororhodium(I)

[1-²H₁]-2-phenylethanal

phenylacetaldehyde

Downstream raw materials:

Wilkinson's catalyst

chloro(η-ethylene)bis(triphenylphosphine)rhodium(I)

Rh(CO)(P(C₆H₅)3)2Br₃

Tetramethyl ethylenetetracarboxylate