10-Phenylphenoxazine

Base Information

• Chemical Name: 10-Phenylphenoxazine
• CAS No.: 37832-25-0
• Molecular Formula: C18H13NO
• Molecular Weight: 259.307
• DSSTox Substance ID: DTXSID901315164
• Nikkaji Number: J3.227.491I
• Mol file: 37832-25-0.mol

Synonyms:10-phenylphenoxazine;10-phenyl-10H-phenoxazine;n-phenyl phenoxazine;Oprea1_134980;Oprea1_791729;SCHEMBL1573992;DTXSID901315164;AS-0406;37832-25-0;InChI=1/C18H13NO/c1-2-8-14(9-3-1)19-15-10-4-6-12-17(15)20-18-13-7-5-11-16(18)19/h1-13

Chemical Property of 10-Phenylphenoxazine

Chemical Property:

• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 259.099714038
• Heavy Atom Count: 20
• Complexity: 303

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)N2C3=CC=CC=C3OC4=CC=CC=C42

Technology Process of 10-Phenylphenoxazine

There total 11 articles about 10-Phenylphenoxazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2,2'-dibromodiphenyl ether (51452-87-0) + aniline (62-53-3) → 10-phenyl-10H-phenoxazine (37832-25-0)

Guidance literature:

With DPEphos; palladium diacetate; sodium t-butanolate; In toluene; at 120 ℃; for 15h; Reagent/catalyst; Solvent; Catalytic behavior; Schlenk technique; Inert atmosphere;

DOI:10.1039/c7ob01540b

Reference yield: 98.0%

iodobenzene (591-50-4) + 2-[N-(2-chlorophenyl)amino]phenol → 10-phenyl-10H-phenoxazine (37832-25-0)

Guidance literature:

With copper(l) iodide; caesium carbonate; at 110 ℃; for 24h; Reagent/catalyst; Solvent; Schlenk technique; Inert atmosphere;

DOI:10.1039/c4ra09593f

Reference yield: 95.0%

bromobenzene (108-86-1,52753-63-6) + phenoxazine (135-67-1) → 10-phenyl-10H-phenoxazine (37832-25-0)

Guidance literature:

With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate; In toluene; Reflux; Inert atmosphere;

upstream raw materials:

phenoxazine

iodobenzene

2-amino-phenol

2-((2-bromophenyl)amino)phenol

Downstream raw materials:

10-phenyl-phenoxazine-4-carboxylic acid

10-(phenyl)phenoxazine-4,6-dicarboxylic acid

10-phenyl-3-thiocyanato-10H-phenoxazine

7,7'-dichloro-10,10'-diphenyl-10H,10'H-[3,3']biphenoxazinyl