51452-87-0Relevant articles and documents
The Importance of Excited-State Energy Alignment for Efficient Exciplex Systems Based on a Study of Phenylpyridinato Boron Derivatives
Mamada, Masashi,Tian, Guojian,Nakanotani, Hajime,Su, Jianhua,Adachi, Chihaya
, p. 12380 - 12384 (2018)
Understanding excited-state dynamics is critical for improving the photoluminescence (PL) efficiency of exciplexes. A series of exciplexes based on conventional hole-transporting materials as donor and newly developed phenylpyridinato boron derivatives as acceptor were investigated. High PL efficiencies were achieved in only some combinations, and a large difference in performance among combinations provided insight into nonradiative processes in exciplex systems. Furthermore, the triplet local excited states (3LE) of each donor and acceptor were found play an important role in triplet exciplex harvesting. Significant contributions from triplets were clearly observed when the charge-transfer excited states (1CT and 3CT) and 3LE were ideally aligned. We also demonstrated fine control of relative energy alignment via the concentration to improve the PL efficiency.
Organic electroluminescent compound, applications thereof, and organic electroluminescent device
-
Paragraph 0083; 0084; 0087, (2020/03/17)
The invention relates to the field of o organic electroluminescent devices and discloses an organic electroluminescent compound, applications thereof, and an organic electroluminescent device. The compound has the structure shown as the formula (I), where
Pd-Catalyzed double N-arylation of primary amines to synthesize phenoxazines and phenothiazines
Zhang, Lu,Huang, Xin,Zhen, Shan,Zhao, Jing,Li, Heng,Yuan, Bingxin,Yang, Guanyu
supporting information, p. 6306 - 6309 (2017/08/10)
An efficient and versatile Pd-catalyzed tandem C-N bond formation between aryl halides and primary amines is developed. The transformation allows a one-pot synthesis of phenoxazine and phenothiazine derivatives with a broad range of substitution patterns from readily available precursors.