Phenanthrene, 9-(4-chlorophenyl)-

Base Information

• Chemical Name: Phenanthrene, 9-(4-chlorophenyl)-
• CAS No.: 37842-69-6
• Molecular Formula: C20H13Cl
• Molecular Weight: 288.776
• Mol file: 37842-69-6.mol

Synonyms:

Chemical Property of Phenanthrene, 9-(4-chlorophenyl)-

Chemical Property:

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phenanthrene, 9-(4-chlorophenyl)-

There total 24 articles about Phenanthrene, 9-(4-chlorophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2-[(4-chlorophenyl)ethynyl]-1,1'-biphenyl (1420770-81-5) → 9-(4'-chlorophenyl)phenanthrene (37842-69-6)

Guidance literature:

With copper(II) bis(trifluoromethanesulfonate); eosin y; In dichloromethane; at 60 ℃; for 72h; Sealed tube; Irradiation; Inert atmosphere;

DOI:10.1039/c6cc03725a

Reference yield: 91.0%

9-bromophenanthrene (573-17-1) + 4-Chlorophenylboronic acid (1679-18-1) → 9-(4'-chlorophenyl)phenanthrene (37842-69-6)

Guidance literature:

With potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In water; toluene; at 100 ℃; for 3h; Inert atmosphere; Sealed tube;

Reference yield: 87.0%

bromochlorobenzene (106-39-8) + 9-phenanthrenylboronic acid (68572-87-2) → 9-(4'-chlorophenyl)phenanthrene (37842-69-6)

Guidance literature:

bromochlorobenzene; 9-phenanthrenylboronic acid; With sodium carbonate; In tetrahydrofuran; water; at 20 ℃; for 0.0833333h; Inert atmosphere;

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; water; at 65 ℃; for 10h;

upstream raw materials:

(9-p-Chlorophenyl-9-fluorenyl)acetaldehyd

1-bromo-2-(2-(4-chlorophenyl)-2-phenylethyl)benzene

9-bromophenanthrene

4-Chlorophenylboronic acid

Downstream raw materials:

C₂₆H₁₉N