1-CHLORO-4-(4-PHENYL-1,3-BUTADIENYL)BENZENE

Base Information

• Chemical Name: 1-CHLORO-4-(4-PHENYL-1,3-BUTADIENYL)BENZENE
• CAS No.: 37985-13-0
• Molecular Formula: C16H13Cl
• Molecular Weight: 240.732
• Mol file: 37985-13-0.mol

Synonyms:(1E,3E)-4-(4-chlorophenyl)-1-phenyl-1,3-butadiene;all-trans-1-(p-chlorophenyl)-4-phenyl-1,3-butadiene;(1E,3E)-1-(4-chlorophenyl)-4-phenylbuta-1,3-diene;1t-(4-chloro-phenyl)-4t-phenyl-buta-1,3-diene;(E,E)-1-(p-chlorophenyl)-4-phenyl-1,3-butadiene;trans,trans-1-(p-chorophenyl)-4-phenyl-butadiene;

Chemical Property of 1-CHLORO-4-(4-PHENYL-1,3-BUTADIENYL)BENZENE

Chemical Property:

• PSA: 0.00000
• LogP: 5.06660

Purity/Quality:

98% ^*data from raw suppliers

1-Chloro-4-((1E,3E)-4-phenylbuta-1,3-dien-1-yl)benzene 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-CHLORO-4-(4-PHENYL-1,3-BUTADIENYL)BENZENE

There total 26 articles about 1-CHLORO-4-(4-PHENYL-1,3-BUTADIENYL)BENZENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

4-vinylbenzyl chloride (1073-67-2,24991-47-7) + trans 2-phenylethenesulfonyl chloride (52147-97-4) → (1E,3E)-1-chloro-4-(4-phenylbuta-1,3-dien-1-yl)benzene (37985-13-0)

Guidance literature:

tris(triphenylphosphine)ruthenium(II) chloride; In benzene; at 150 ℃; for 43h;

DOI:10.1246/cl.1985.705

Reference yield: 92.0%

[2-(4-chloro-phenyl)-cyclopropyl]-phenyl-methanol → (1E,3E)-1-chloro-4-(4-phenylbuta-1,3-dien-1-yl)benzene (37985-13-0)

Guidance literature:

With In(OSO₂CF₃)3; In dichloromethane; for 0.416667h; ultrasound;

DOI:10.1002/ejoc.200600037

Reference yield: 85.0%

3-phenyl-propenal (104-55-2) + (4-chlorobenzyl)zinc(II) bromide → (1E,3E)-1-chloro-4-(4-phenylbuta-1,3-dien-1-yl)benzene (37985-13-0)

Guidance literature:

With chloro-trimethyl-silane; bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; at 20 ℃; for 8h;

DOI:10.1002/adsc.200606016

upstream raw materials:

(E)-3-phenylpropenal

(4-chlorobenzyl)triphenylphosphonium bromide

4-chlorobenzaldehyde

(E)-cinnamyltriphenylphosphonium bromide

Downstream raw materials:

trans-1-(p-Chlorphenyl)-4-phenylbut-2-en

(E)-1-(buta-1,3-dien-1-yl)-4-chlorobenzene

(E)-3-phenylpropenal

4-chlorobenzaldehyde