2-Cyclohexen-1-one, 2-(2-propenyl)-

Base Information

• Chemical Name: 2-Cyclohexen-1-one, 2-(2-propenyl)-
• CAS No.: 38019-50-0
• Molecular Formula: C9H12O
• Molecular Weight: 136.194
• Mol file: 38019-50-0.mol

Synonyms:

Chemical Property of 2-Cyclohexen-1-one, 2-(2-propenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-Cyclohexen-1-one, 2-(2-propenyl)-

There total 21 articles about 2-Cyclohexen-1-one, 2-(2-propenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

cyclohexenone (930-68-7) + allyl bromide (106-95-6) → 2-allyl-cyclohex-2-enone (38019-50-0) + 2-(3'-oxocyclohexyl)-2-cyclohexen-1-one (5216-84-2)

Guidance literature:

With caesium carbonate; (+)-exo-3-(Methylthio)-1,7,7-trimethylbicyclo<2.2.1>heptan-2-ol; In acetonitrile; tert-butyl alcohol; at 80 ℃; for 24h; Reagent/catalyst;

DOI:10.1002/ejoc.201301743

Reference yield: 76.0%

2-methoxybenzoic acid methyl ester (606-45-1) → 2-allyl-cyclohex-2-enone (38019-50-0)

Guidance literature:

2-methoxybenzoic acid methyl ester; With ammonia; sodium; tert-butyl alcohol; In tetrahydrofuran; at -78 ℃;

With potassium hydroxide; water; isopropyl alcohol; Heating / reflux;

With hydrogenchloride; water; In tetrahydrofuran; Heating / reflux;

Reference yield: 52.0%

2-allylcyclohexan-1-one (94-66-6) → 2-allyl-cyclohex-2-enone (38019-50-0) + Bicyclo[3.3.1]non-2-en-9-one (4844-11-5) + 2-Acetoxy-6-allylcyclohexanone + 5-Acetoxybicyclo<3.3.1>non-2-en-9-one

Guidance literature:

With copper diacetate; manganese triacetate; In acetic acid; at 80 ℃; Further byproducts given;

DOI:10.1021/jo00122a006

upstream raw materials:

cyclohexenone

allyl bromide

allyl iodid

2-(phenylselanyl)cyclohex-2-en-1-one

Downstream raw materials:

3-Allyl-2-chloro-cyclohexa-1,3-dienecarbaldehyde

(S)-2-Allyl-cyclohex-2-enol

2-(prop-2'-enyl)-cyclohex-2-en-1-ol

trans-3-Methyl-2-(2-propenyl)cyclohexanone