Benzene, 1,1',1''-(1-methyl-2-propen-1-yl-3-ylidene)tris-

Base Information

• Chemical Name: Benzene, 1,1',1''-(1-methyl-2-propen-1-yl-3-ylidene)tris-
• CAS No.: 38328-28-8
• Molecular Formula: C22H20
• Molecular Weight: 284.401
• Mol file: 38328-28-8.mol

Synonyms:

Chemical Property of Benzene, 1,1',1''-(1-methyl-2-propen-1-yl-3-ylidene)tris-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzene, 1,1',1''-(1-methyl-2-propen-1-yl-3-ylidene)tris-

There total 15 articles about Benzene, 1,1',1''-(1-methyl-2-propen-1-yl-3-ylidene)tris- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 1,1-Diphenylethylene (530-48-3) → but-1-ene-1,1,3-triyltribenzene (38328-28-8)

Guidance literature:

With Snβ zeolite; In 1,2-dichloro-ethane; at 100 ℃; for 15h; Reagent/catalyst; regioselective reaction; Sealed tube;

DOI:10.1039/c5ra24948a

Reference yield: 82.0%

2-Phenylpropanal (34713-70-7) + phenyl 3-phenylprop-2-ynoate (100954-03-8) → but-1-ene-1,1,3-triyltribenzene (38328-28-8)

Guidance literature:

With di-tert-butyl peroxide; In fluorobenzene; at 130 ℃; for 20h; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.joc.6b02451

Reference yield: 80.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 1,1-Diphenylethylene (530-48-3) → 1,3-diphenyl-1-butene (7614-93-9) + but-1-ene-1,1,3-triyltribenzene (38328-28-8)

Guidance literature:

With indium(III) triflate; In 1,4-dioxane; at 120 ℃; for 24h; Sealed vial;

DOI:10.1002/chem.201101190

upstream raw materials:

1,1,3-triphenylbutan-1-ol

benzalacetophenone

methyl iodide

phenylytterbium iodide