Imidodiphosphorous tetrafluoride

Base Information

• Chemical Name: Imidodiphosphorous tetrafluoride
• CAS No.: 34326-59-5
• Molecular Formula: F4HNP2
• Molecular Weight: 152.956
• DSSTox Substance ID: DTXSID70187892
• Nikkaji Number: J2.216.183K
• Wikidata: Q83059641
• Mol file: 34326-59-5.mol

Synonyms:Imidodiphosphorous tetrafluoride;34326-59-5;Bis(difluorophosphino)amine;DTXSID70187892;N H (P F2)2

Chemical Property of Imidodiphosphorous tetrafluoride

Chemical Property:

• XLogP3: 1.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 152.95203568
• Heavy Atom Count: 7
• Complexity: 39

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N(P(F)F)P(F)F

Technology Process of Imidodiphosphorous tetrafluoride

There total 3 articles about Imidodiphosphorous tetrafluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(difluorophosphino)silylamine (71579-72-1) + water (7732-18-5) → disiloxane (107-46-0) + aminodifluorophosphine (25757-74-8) + μ-oxo-bis(difluorophosphane) (13812-07-2) + bis(difluorophosphino)amine (34326-59-5) + trifluorophosphane (7783-55-3)

Guidance literature:

In chloroform-d1; absence of air and moisture; room temp.; not isolated, reaction followed by (1)H- and (31)P-NMR spectroscopy; further products: SiH4, SiFH3;

DOI:10.1039/DT9790001065

Reference yield:

aminodifluorophosphine (25757-74-8) + bromodifluorophosphine (15597-40-7) → bis(difluorophosphino)amine (34326-59-5)

Guidance literature:

With trimethylamine; fourfold excess of NH2PF2; the excess of primary amine was destroyed with hydrogen bromide, puritywas checked by IR and NMR;

DOI:10.1039/DT9800000954

Reference yield:

bis(difluorophosphino)germylamine (66463-54-5) → germylene + bis(difluorophosphino)amine (34326-59-5)

Guidance literature:

In neat (no solvent); absence of air and moisture;

DOI:10.1039/DT9770002348

upstream raw materials:

aminodifluorophosphine

bromodifluorophosphine

bis(difluorophosphino)silylamine

water

Downstream raw materials:

fluorosilane

bis(difluorophosphino)silylamine

trifluorophosphane

difluoro(difluorophosphinoamino)borane