4-(1-PHENYLMETHANOYL)BENZOYL CHLORIDE

Base Information

• Chemical Name: 4-(1-PHENYLMETHANOYL)BENZOYL CHLORIDE
• CAS No.: 39148-58-8
• Molecular Formula: C14H9ClO2
• Molecular Weight: 244.677
• Mol file: 39148-58-8.mol

Synonyms:p-benzoylbenzoyl chloride;benzophenone-4-carbonyl chloride;4-benzoyl benzoyl chloride;4-(1-PHENYLMETHANOYL)BENZOYL CHLORIDE;Benzoyl chloride,4-benzoyl;4-chloroformylbenzophenone;4-benzoylbenzoic acid chloride;

Chemical Property of 4-(1-PHENYLMETHANOYL)BENZOYL CHLORIDE

Chemical Property:

• PSA: 34.14000
• LogP: 3.29660

Purity/Quality:

99% ^*data from raw suppliers

BENZOYL CHLORIDE,4-BENZOYL- 95 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-(1-PHENYLMETHANOYL)BENZOYL CHLORIDE

There total 7 articles about 4-(1-PHENYLMETHANOYL)BENZOYL CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.1%

4-carboxybenzophenone (611-95-0) → 4-benzoylbenzoyl chloride (39148-58-8)

Guidance literature:

With phosphorus pentachloride; In diethyl ether;

DOI:10.1021/jm00061a001

Reference yield:

oxalyl dichloride (79-37-8) + 4-carboxybenzophenone (611-95-0) → 4-benzoylbenzoyl chloride (39148-58-8)

Guidance literature:

With N,N-dimethyl-formamide; In tetrahydrofuran; at 120 ℃; for 1h;

Reference yield:

4-Methylbenzophenone (134-84-9) → 4-benzoylbenzoyl chloride (39148-58-8)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium dichromate

2: phosphorous pentachloride

With sodium dichromate; phosphorus pentachloride;

DOI:10.1080/00268948208072592

upstream raw materials:

4-carboxybenzophenone

4-Methylbenzophenone

phosgene

benzyltrimethylammonium chloride

Downstream raw materials:

4-mesitoylbenzophenone

(4-Benzoyl-phenyl)-(2,4,6-triisopropyl-phenyl)-methanone

N-(1-naphthoyl)-N-phenyl-O-(4-benzoylbenzoyl)hydroxylamine

4-Benzoyl-benzoic acid (2E,6E)-8-(2-chloro-acetoxy)-2,6-dimethyl-octa-2,6-dienyl ester

Refernces

• 1、 Ayadim,Soumillion. "Photosensitizers covalently anchored to the silica surface: Modulation of the excited state efficiency through electron transfer from the linking arm or from the surface.". . p. 4615 - 4618. Retrieved 1995.
• 2、 Flavell, Robert R.,Liu, Jianbo,Parker, Matthew F. L.,Toste, F. Dean,Wang, Sinan,Wilson, David M.. "Synthesis of N-trifluoromethyl amides from carboxylic acids". supporting information. p. 2245 - 2255. Retrieved 2021/08/12.
• 3、 Huy, Peter H.,Mbouhom, Christelle. "Formamide catalyzed activation of carboxylic acids-versatile and cost-efficient amidation and esterification". . p. 7399 - 7406. Retrieved 2019/08/20.