(3-(BENZOYLOXY)PROPYL)TRIPHENYLPHOSPHONIUM BROMIDE

Base Information

• Chemical Name: (3-(BENZOYLOXY)PROPYL)TRIPHENYLPHOSPHONIUM BROMIDE
• CAS No.: 30698-18-1
• Molecular Formula: C28H26 O2 P . Br
• Molecular Weight: 505.391
• Hs Code.: 2931900090
• Mol file: 30698-18-1.mol

Synonyms:Phosphonium,(3-hydroxypropyl)triphenyl-, bromide, benzoate (8CI); Phosphonium,[3-(benzoyloxy)propyl]triphenyl-, bromide (9CI); NSC 145200

Chemical Property of (3-(BENZOYLOXY)PROPYL)TRIPHENYLPHOSPHONIUM BROMIDE

Chemical Property:

• Melting Point: 178.0-180.1 °C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 39.89000
• Density: g/cm³
• LogP: 2.23160

Purity/Quality:

99.3% ^*data from raw suppliers

(3-(BENZOYLOXY)PROPYL)TRIPHENYLPHOSPHONIUM BROMIDE AldrichCPR ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (3-(BENZOYLOXY)PROPYL)TRIPHENYLPHOSPHONIUM BROMIDE

There total 4 articles about (3-(BENZOYLOXY)PROPYL)TRIPHENYLPHOSPHONIUM BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

sodium benzoate (532-32-1) + 3-bromopropyltriphenylphosphonium bromide (3607-17-8) → bromure de benzoyloxy-3 propyltriphenylphosphonium (30698-18-1)

Guidance literature:

In water; acetone; for 15h; Heating;

DOI:10.1016/S0040-4020(01)92355-5

Reference yield:

triphenylphosphine (603-35-0) → bromure de benzoyloxy-3 propyltriphenylphosphonium (30698-18-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 80 percent / toluene / 15 h / Heating

2: 76 percent / acetone; H₂O / 15 h / Heating

In water; acetone; toluene;

DOI:10.1016/S0040-4020(01)92355-5

Reference yield:

3-bromopropyl benzoate (6065-69-6) + triphenylphosphine (603-35-0) → bromure de benzoyloxy-3 propyltriphenylphosphonium (30698-18-1)

Guidance literature:

Heating;

DOI:10.1021/jo800514k

upstream raw materials:

sodium benzoate

3-bromopropyltriphenylphosphonium bromide

triphenylphosphine

3-bromopropyl benzoate

Downstream raw materials:

methyl (2S,3S,5S,6Z)-5-acetoxy-9-benzoyloxy-2,3-isopropylidenedioxy-6-nonenoate

methyl (2S,3S,5R,6Z)-5-acetoxy-9-benzoyloxy-2,3-isopropylidenedioxy-6-nonenoate

2,2,2-Triphenyl-1,2-λ⁵-oxaphospholan

cyclopropyl phenyl ketone