4'-Methyl-4-biphenylboronic acid

Base Information

Chemical Name:4'-Methyl-4-biphenylboronic acid
CAS No.:393870-04-7
Molecular Formula:C13H13BO2
Molecular Weight:212.05200
Hs Code.:2931900090
Mol file:393870-04-7.mol

Synonyms:4'-METHYL-4-BIPHENYLBORONIC ACID;

Suppliers and Price of 4'-Methyl-4-biphenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(4''-Methyl-[1,1''-biphenyl]-4-yl)boronicAcid
10mg
$ 45.00

TCI Chemical
4'-Methyl-4-biphenylboronic Acid (contains varying amounts of Anhydride)
5G
$ 347.00

TCI Chemical
4'-Methyl-4-biphenylboronic Acid (contains varying amounts of Anhydride)
1G
$ 99.00

Crysdot
(4'-Methyl-[1,1'-biphenyl]-4-yl)boronicacid 95+%
1g
$ 228.00

Crysdot
(4'-Methyl-[1,1'-biphenyl]-4-yl)boronicacid 95+%
10g
$ 1208.00

Crysdot
(4'-Methyl-[1,1'-biphenyl]-4-yl)boronicacid 95+%
5g
$ 713.00

ChemScene
[4-(4-Methylphenyl)phenyl]boronicacid
5g
$ 246.00

Chem-Impex
4'-Methyl-4-biphenylboronicacid,97-105%(Assaybytitration) 97-105%(Assaybytitration)
5G
$ 399.84

Chem-Impex
4'-Methyl-4-biphenylboronicacid,97-105%(Assaybytitration) 97-105%(Assaybytitration)
1G
$ 104.16

Chemenu
(4''-Methyl-[1,1''-biphenyl]-4-yl)boronicacid 95+%
1g
$ 67.00

Total 37 raw suppliers

Chemical Property of 4'-Methyl-4-biphenylboronic acid

Chemical Property:

Melting Point:138 °C
Boiling Point:393.8±45.0 °C(Predicted)
PKA:8.62±0.17(Predicted)
PSA：40.46000
Density:1.15±0.1 g/cm3(Predicted)
LogP:1.34180
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

97% ^*data from raw suppliers

(4''-Methyl-[1,1''-biphenyl]-4-yl)boronicAcid ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 4'-Methyl-4-biphenylboronic acid

There total 9 articles about 4'-Methyl-4-biphenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: p-(p-Tol)C₆H₄B(N-methyliminodiacetate)

: 393870-04-7
(4'-methyl[1,1'-biphenyl]-4-yl)boronic acid

Guidance literature:: With water; sodium hydroxide; In tetrahydrofuran; at 23 ℃; for 0.166667h;
DOI:10.1002/0471264229.os086.33

Reference yield: 77.0%

: C₃₂H₂₈B₂O₆^(2-)*2K⁽¹⁺⁾

: 393870-04-7
(4'-methyl[1,1'-biphenyl]-4-yl)boronic acid

Guidance literature:: With hydrogenchloride; In water; pH=3;

Reference yield: 50.0%

: 121-43-7,63156-11-6
Trimethyl borate

: 50670-49-0
4-bromo-4'-methylbiphenyl

: 393870-04-7
(4'-methyl[1,1'-biphenyl]-4-yl)boronic acid

Guidance literature:: 4-bromo-4'-methylbiphenyl; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 2h; Inert atmosphere;

Trimethyl borate; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;

With water;
DOI:10.1021/acs.orglett.5b03152