Phosphorimidic trichloride, (trimethylsilyl)-

Base Information

Chemical Name:Phosphorimidic trichloride, (trimethylsilyl)-
CAS No.:40678-60-2
Molecular Formula:C3H9Cl3NPSi
Molecular Weight:224.529
Hs Code.:
DSSTox Substance ID:DTXSID80472201
Nikkaji Number:J851.202G
Mol file:40678-60-2.mol

Synonyms:Phosphorimidic trichloride, (trimethylsilyl)-;40678-60-2;SCHEMBL715713;DTXSID80472201;SOPLWKIXDXHNTF-UHFFFAOYSA-N;N-(trimethylsilyl)-trichlorophosphoranimine;Tris(chloro)-N-(trimethylsilyl)phosphoranimine

Suppliers and Price of Phosphorimidic trichloride, (trimethylsilyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of Phosphorimidic trichloride, (trimethylsilyl)-

Chemical Property:

PSA：22.17000
LogP:4.48390
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:222.930746
Heavy Atom Count:9
Complexity:137

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)N=P(Cl)(Cl)Cl

Technology Process of Phosphorimidic trichloride, (trimethylsilyl)-

There total 1 articles about Phosphorimidic trichloride, (trimethylsilyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

: 1586-73-8
tris(trimethylsilyl)amine

: 10026-13-8,874483-75-7
phosphorus pentachloride

: 940-71-6,16422-79-0
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

: 40678-60-2
trichloro(trimethylsilyl)phosphoranimine

Guidance literature:: In dichloromethane; inert atmosphere; dropwise addn. of 0.5-1 equiv. PCl5 to amine at -78 or25°C, stirring for 30 min to 12 h; yields depending on educt rat io, reaction temp., time and rate of addn.; product mixt. not sepd., detd. by (31)P-NMR spectroscopy;

Reference yield: 89.0%

: 40678-60-2
trichloro(trimethylsilyl)phosphoranimine

: 603-35-0
triphenylphosphine

: 73685-86-6
dichloro(triphenylphosphoranylimino)phosphane

Guidance literature:: In dichloromethane; for 3h;
DOI:10.1021/ja039549z

Reference yield:

: 40678-60-2
trichloro(trimethylsilyl)phosphoranimine

: 940-71-6,16422-79-0
2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

: 2950-45-0
octachlorocyclotetraphosphazene

Guidance literature:: With [PCl₂(NP(C₆H₅)3)2]Cl; In dichloromethane; (N2); a soln. of Si compd. added dropwise to a soln. of PCl2(NP(C6H5)3)2Cl, stirred for 24 h at 25°C; not isolated, detected by NMR;