(Z)-2-Nonenenitrile

Base Information

• Chemical Name: (Z)-2-Nonenenitrile
• CAS No.: 40856-15-3
• Molecular Formula: C9H15N
• Molecular Weight: 137.225
• Mol file: 40856-15-3.mol

Synonyms:non-2c-enenitrile;Non-2c-ennitril;cis-non-2-enitrile;non-2-enenitrile;(Z)-2-Nonenenitrile;Non-2-ennitril;(Z)-Non-2-enenitrile;

Chemical Property of (Z)-2-Nonenenitrile

Chemical Property:

• Boiling Point: 58 °C (2 mmHg)
• PSA: 23.79000
• LogP: 3.03658

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (Z)-2-Nonenenitrile

There total 15 articles about (Z)-2-Nonenenitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

oct-1-ene (111-66-0,25068-25-1) + acrylonitrile (107-13-1,25014-41-9) → (Z)-non-2-enenitrile (40856-15-3,29127-83-1) + (E)-non-2-enenitrile (40856-16-4,29127-83-1) + (E)-7-tetradecene (41446-63-3) + (Z)-7-tetradecene (10374-74-0,41446-63-3,41446-60-0)

Guidance literature:

bis[1,1-di(trifluoromethyl)ethoxy][(2,6-diisopropylphenyl)imino](2-methyl-2-phenylpropylidene)molybdenum; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; In hexane; at 20 ℃; for 3h;

Reference yield:

oct-1-ene (111-66-0,25068-25-1) + acrylonitrile (107-13-1,25014-41-9) → (Z)-non-2-enenitrile (40856-15-3,29127-83-1) + (E)-7-tetradecene (41446-63-3)

Guidance literature:

With Mo(CHCMe2Ph)2; In diethyl ether; for 10h; Ambient temperature;

DOI:10.1021/ja00123a023

Reference yield:

oct-1-ene (111-66-0,25068-25-1) + acrylonitrile (107-13-1,25014-41-9) → (Z)-non-2-enenitrile (40856-15-3,29127-83-1) + (E)-non-2-enenitrile (40856-16-4,29127-83-1)

Guidance literature:

2-methylpyridine ruthenium benzylidene complex; In dichloromethane; at 40 ℃; for 12h; Further Variations:; Catalysts; Reaction partners; Product distribution;

DOI:10.1016/j.tetlet.2007.04.065

upstream raw materials:

heptanal

cyanoacetic acid

oct-1-ene

cyanogen chloride

Refernces

• 1、 Rountree, Sandra M.,Taylor, Sarah F.R.,Hardacre, Christopher,Lagunas, M. Cristina,Davey, Paul N.. "Synthesis of α,β-unsaturated aldehydes and nitriles via cross-metathesis reactions using Grubbs' catalysts". . p. 94 - 104. Retrieved 2015/09/28.
• 2、 Zhang, Wen-Zhen,He, Ren,Zhang, Rong. "Benzylideneruthenium complexes bearing pyridine-based ligands and their influence on the formation of mono- or bis(pyridine) complexes". . p. 5345 - 5352. Retrieved 2008/09/17.