Benzyl(bromo)mercury

Base Information

Chemical Name:Benzyl(bromo)mercury
CAS No.:4109-72-2
Molecular Formula:C7H7BrHg
Molecular Weight:371.627
Hs Code.:
DSSTox Substance ID:DTXSID10518742
Mol file:4109-72-2.mol

Synonyms:Benzyl(bromo)mercury;4109-72-2;benzylmercury bromide;DTXSID10518742

Suppliers and Price of Benzyl(bromo)mercury

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of Benzyl(bromo)mercury

Chemical Property:

PSA：0.00000
LogP:-1.12560
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:371.94376
Heavy Atom Count:9
Complexity:69.3

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)C[Hg]Br

Technology Process of Benzyl(bromo)mercury

There total 5 articles about Benzyl(bromo)mercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 116670-02-1
{(η5-C5Me5)Os(CO)(PMe2Ph)CH2Ph}

: mercury dibromide

: 107087-80-9
{(η5-C5Me5)Os(CO)(PMe2Ph)Br}

: 4109-72-2
PhCH₂HgBr

Guidance literature:: In dichloromethane-d2; (N2); electrophilic cleavage reaction by addn. of HgBr2 to a soln. of Cp*Os(CO)(PMe2Ph)CH2Ph in CD2Cl2;; not isolated, detected by NMR;;

Reference yield: 24.0%

: dicarbonyl(pentamethylcyclopenta-1,3-diene)benzylosmium

: mercury dibromide

: 81554-89-4
{(η5-C5Me5)Os(CO)2Br}

: 100-39-0
benzyl bromide

: 4109-72-2
PhCH₂HgBr

Guidance literature:: In dichloromethane-d2; (N2); electrophilic cleavage reaction by addn. of HgBr2 to a soln. of Cp*Os(CO)2CH2Ph in CD2Cl2;; not isolated, detected by NMR;;

Reference yield: 17.0%

: 100-39-0
benzyl bromide

: mercury

: 780-24-5
dibenzylmercury(II)

: 4109-72-2
PhCH₂HgBr

Guidance literature:: With catalyst: Et₄NBr; In N,N-dimethyl-formamide; mixt. of benzyl bromide and Hg in satd. soln. of Et4NBr in dry DMF agitated (sealed ampoule, Ar, in the dark, 100 h);; ppt. filtered off, washed with ether, dried, (chromy. of the mother liquor: silica gel, CHCl3-hexane (2:1), protected from light);;
DOI:10.1007/BF00947734