CHLORIDE IONOPHORE I

Base Information

• Chemical Name: CHLORIDE IONOPHORE I
• CAS No.: 32195-55-4
• Molecular Formula: C44H28 Cl Mn N4
• Molecular Weight: 703.11
• Hs Code.: 2934999090
• Mol file: 32195-55-4.mol

Synonyms:Manganese,chloro[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-,(SP-5-12)-; Manganese, chloro[5,10,15,20-tetraphenylporphinato(2-)]- (8CI);21H,23H-Porphine, 5,10,15,20-tetraphenyl-, manganese complex; 21H,23H-Porphine,manganese deriv.; (5,10,15,20-Tetraphenylporphinato)manganese(III) chloride;(Tetraphenylporphyrin)manganese chloride;5,10,15,20-Tetraphenyl-21H,23H-porphine manganese(III) chloride;5,10,15,20-Tetraphenylporphyrinato manganese(III) chloride;Chloro(5,10,15,20-Tetraphenylporphine)manganese;Chloro(5,10,15,20-tetraphenylporphinato)manganese;Chloro(5,10,15,20-tetraphenylporphyrinato)manganese;Chloro(5,10,15,20-tetraphenylporphyrinato)manganese(III);Chloro(meso-tetraphenylporphyrinato)manganese(III);Chloro(tetraphenylporphinato)manganese; Chloro(tetraphenylporphinato)manganese(III);Chloro(tetraphenylporphyrin)manganese(III);Chloro(tetraphenylporphyrinato)manganese;Chloro[5,10,15,20-tetraphenylporphinato(2-)]manganese; KJB 007; NSC 173215;Tetraphenylporphine manganese(III) chloride;Tetraphenylporphyrinatomanganese(III) chloride; meso-Tetraphenylporphyrinmanganese(III) chloride

Chemical Property of CHLORIDE IONOPHORE I

Chemical Property:

• Melting Point: >320 °C
• PSA: 19.72000
• LogP: 6.13430
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

99.5% ^*data from raw suppliers

5,10,15,20-Tetraphenyl-21H,23H-porphine manganese(III) chloride 95% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Tetraphenylporphyrin manganese (III) chloride complex generally finds application in determining histidine in aqueous solutions by resonance light scattering technique.

Technology Process of CHLORIDE IONOPHORE I

There total 32 articles about CHLORIDE IONOPHORE I which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

manganese(II) chloride tetrahydrate + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → (5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride (34557-72-7,32195-55-4)

Guidance literature:

In N,N-dimethyl-formamide; at 150 ℃; for 1h; Inert atmosphere;

DOI:10.1021/acs.inorgchem.8b03184

Reference yield: 85.0%

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + manganese(II) chloride tetrahydrate → 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride (32195-55-4,34557-72-7)

Guidance literature:

In N,N-dimethyl-formamide; soln. stirred at 100°C for 3 h; monitored by chromy.; solvent removed (vac.); purifn. on silica gel using CHCl3 as eluent;

DOI:10.1016/S0020-1693(00)00360-1

Reference yield: 80.0%

5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) + manganese(ll) chloride (7773-01-5) → (5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride (34557-72-7,32195-55-4)

Guidance literature:

With cadmium(II) chloride; In N,N-dimethyl-formamide; for 0.333333h; Reflux;

DOI:10.1134/S1070363215050217

upstream raw materials:

azidomanganese(III) meso-tetraphenylporphyrin

1-Chloronaphthalene

5,10,15,20-tetraphenyl-21H,23H-porphine

[ClMn(meso-tetraphenylporphinato)(OIPh)]2O

Downstream raw materials:

lauric acid

ClMn(IV)(O)(tetraphenylporphyrin)

manganese(II) 5,10,15,20-tetraphenylporphyrinate

manganese(III)tetraphenylporphine(pyridine)⁽¹⁺⁾

Refernces

• 1、 Zhang, Qi-Wei,Elemans, Johannes A. A. W.,White, Paul B.,Nolte, Roeland J. M.. "A manganese porphyrin-α-cyclodextrin conjugate as an artificial enzyme for the catalytic epoxidation of polybutadiene". . p. 5586 - 5589. Retrieved 2018.
• 2、 Donzello, Maria Pia,Bartolino, Laura,Ercolani, Claudio,Rizzoli, Corrado. "A rare μ-hydroxo-bridged species. Synthesis, structure, and properties of μ-hydroxo(tetraphenylporphyrinatomanganese(III))(phthalocyaninato-(azido) chromium(III)), [(TPP)Mn-O(H)-CrPc(N3)]". . p. 6988 - 6995. Retrieved 2006.
• 3、 Zhao, Jianping,Qian, Fei,Guo, Wenping,Li, Jianfeng,Lin, Zeyuan. "Linkage Isomers of 4-Methylimidazolate Mn(II) Porphyrinates: Hindered or Unhindered?". . p. 7465 - 7474. Retrieved 2021/05/26.
• 4、 Attatsi, Isaac Kwaku,Zhu, Weihua,Liang, Xu. "Surface molecular engineering of axial-exchanged Fe(III)Cl- and Mn(III)Cl-porphyrins towards enhanced electrocatalytic ORRs and OERs". supporting information. . Retrieved 2020/03/23.