6-Methylcyclohex-1-ene-1-carbaldehyde

Base Information

Chemical Name:6-Methylcyclohex-1-ene-1-carbaldehyde
CAS No.:41437-90-5
Molecular Formula:C8H12O
Molecular Weight:124.183
Hs Code.:
DSSTox Substance ID:DTXSID50527439
Mol file:41437-90-5.mol

Synonyms:41437-90-5;6-Methylcyclohex-1-ene-1-carbaldehyde;SCHEMBL1783254;DTXSID50527439

Suppliers and Price of 6-Methylcyclohex-1-ene-1-carbaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 6-Methylcyclohex-1-ene-1-carbaldehyde

Chemical Property:

XLogP3:2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:124.088815002
Heavy Atom Count:9
Complexity:136

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1CCCC=C1C=O

Technology Process of 6-Methylcyclohex-1-ene-1-carbaldehyde

There total 11 articles about 6-Methylcyclohex-1-ene-1-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 201230-82-2
carbon monoxide

: 76605-82-8
6-methyl-cyclohex-1-en-1-yl trifluoromethanesulfonate

: 41437-90-5
3-methylcyclohexene-2-carboxaldehyde

Guidance literature:: With N,N,N,N,-tetramethylethylenediamine; α,α′-bis(2-pyridyl(tert-butyl)phosphino)-o-xylene; hydrogen; palladium diacetate; In toluene; at 80 ℃; for 16h; under 3750.38 Torr; Autoclave;
DOI:10.1021/acs.orglett.9b00765

Reference yield:

: 201230-82-2
carbon monoxide

: 76605-82-8
6-methyl-cyclohex-1-en-1-yl trifluoromethanesulfonate

: 591-48-0
3-methyl-1-cyclohexene

: 41437-90-5
3-methylcyclohexene-2-carboxaldehyde

Guidance literature:: With tri-n-butyl-tin hydride; lithium chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 50 ℃; under 2280 Torr;
DOI:10.1021/ja00263a015

Reference yield:

: 583-60-8
2-Methylcyclohexanone

: 41437-90-5
3-methylcyclohexene-2-carboxaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / N,N-dimethylethylenediamine / benzene / 4 h / Heating

2: 1.) NaOMe, 2.) TiCl₃, aq. NH₄OAc / 1.) methanol, 2.) methanol, RT, 1 h

With titanium(III) chloride; ammonium acetate; sodium methylate; N,N`-dimethylethylenediamine; In benzene;
DOI:10.1021/jo00373a007