1-Naphthalenemethanimine, a-phenyl-

Base Information

• Chemical Name: 1-Naphthalenemethanimine, a-phenyl-
• CAS No.: 41839-61-6
• Molecular Formula: C17H13N
• Molecular Weight: 231.297
• Mol file: 41839-61-6.mol

Synonyms:C-Naphthalen-1-yl-C-phenyl-methyleneamine;[1]naphthyl-phenyl ketone-imine;naphthalen-1-yl(phenyl)methanimine;Phenyl-α-naphthyl-ketimid;1-naphthyl-1-(2-hydroxyphenyl)-methylidenamine;[1]Naphthyl-phenyl-keton-imin;

Chemical Property of 1-Naphthalenemethanimine, a-phenyl-

Chemical Property:

• Melting Point: 66 - 68 °C
• Boiling Point: 181.5 °C(Press: 4.5 Torr)
• PSA: 23.85000
• Density: 1.06±0.1 g/cm3(Predicted)
• LogP: 4.35570

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-Naphthalenemethanimine, a-phenyl-

There total 7 articles about 1-Naphthalenemethanimine, a-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

1-Bromonaphthalene (90-11-9) + benzonitrile (100-47-0) → 1-(1-naphthyl)-1-(2-(1-hydroxyphenyl))methylenimine (41839-61-6)

Guidance literature:

1-Bromonaphthalene; With magnesium; In tetrahydrofuran; Reflux;

benzonitrile; In tetrahydrofuran; for 4h; Reflux;

DOI:10.1002/chir.22529

Reference yield: 73.0%

salicylonitrile (611-20-1) + 1-Bromonaphthalene (90-11-9) → 1-(1-naphthyl)-1-(2-(1-hydroxyphenyl))methylenimine (41839-61-6)

Guidance literature:

1-Bromonaphthalene; With n-butyllithium; In diethyl ether; at -78 - -50 ℃;

salicylonitrile; In diethyl ether; at -50 - 20 ℃; for 2h;

With methanol; In diethyl ether; for 0.5h; Further stages.;

DOI:10.1016/j.tetasy.2008.06.024

Reference yield: 68.0%

benzonitrile (100-47-0) + 1-naphthylmagnesiumbromide (703-55-9) → 1-(1-naphthyl)-1-(2-(1-hydroxyphenyl))methylenimine (41839-61-6)

Guidance literature:

upstream raw materials:

benzonitrile

1-naphthylmagnesiumbromide

1-Cyanonaphthalene

bromobenzene

Downstream raw materials:

N-(3-Dimethylaminopropyl)-α-naphthyl-phenyl-ketoimin

α-Methoxy-N-(1-naphthylphenylmethylen)benzylamin

4-Chlor-α-methoxy-N-(1-naphthylphenylmethylen)benzylamin

α-Methoxy-N-(1-naphthylphenylmethylen)-4-nitrobenzylamin