(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane

Base Information

Chemical Name:(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane
CAS No.:447440-43-9
Molecular Formula:C13H18ClNOSi
Molecular Weight:267.831
Hs Code.:
European Community (EC) Number:684-530-3
DSSTox Substance ID:DTXSID10438299
Nikkaji Number:J1.762.979D
Mol file:447440-43-9.mol

Synonyms:447440-43-9;(4S,5S)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-1-OXA-3-AZA-2-SILACYCLOPENTANE;(4S,5S)-2-chloro-3,4-dimethyl-5-phenyl-2-prop-2-enyl-1,3,2-oxazasilolidine;(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine;(4S,5S)-2-Chloro-3,4-dimethyl-5-phenyl-2-(prop-2-en-1-yl)-1,3,2-oxazasilolidine;SCHEMBL2682527;DTXSID10438299;XHCRAANIMMYPDV-APBZJUGRSA-N;AKOS025295337;(4s, 5s)-2-allyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]oxazasilolidine;(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]oxazasilolidine;(S,S)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE;(S,S)-2-PHENYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE;2-Allyl-2-chloro-3,4beta-dimethyl-5alpha-phenyl-1-oxa-2-sila-3-azacyclopentane

Suppliers and Price of (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)
5g
$ 365.00

Strem Chemicals
(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)
1g
$ 91.00

Total 9 raw suppliers

Chemical Property of (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane

Chemical Property:

Refractive Index:n20/D1.517
Boiling Point:120°C/5 mmHg
Flash Point:38℃
PSA：12.47000
Density:1.095 g/mL at 25 °C
LogP:3.37980
Sensitive.:moisture sensitive, store cold
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:267.0846184
Heavy Atom Count:17
Complexity:283

Purity/Quality:

98%,99%, ^*data from raw suppliers

(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:F,Xi
Statements: 10-15-36/37/38
Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CC1C(O[Si](N1C)(CC=C)Cl)C2=CC=CC=C2
Isomeric SMILES:C[C@H]1[C@@H](O[Si](N1C)(CC=C)Cl)C2=CC=CC=C2
Uses Leighton′s Strained Silacycles: Powerful Enantioselective Allylation ReagentsPractical, enantioselective allylation of acylhydrazonesEnantioselective allylation of ketimines: synthesis of tertiary carbinamines

Technology Process of (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane

There total 2 articles about (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%