Stannane, [2,6-bis(methoxymethyl)phenyl]triphenyl-

Base Information

Chemical Name:Stannane, [2,6-bis(methoxymethyl)phenyl]triphenyl-
CAS No.:473332-52-4
Molecular Formula:C28H28O2Sn
Molecular Weight:515.239
Hs Code.:
DSSTox Substance ID:DTXSID70476091
Mol file:473332-52-4.mol

Synonyms:Stannane, [2,6-bis(methoxymethyl)phenyl]triphenyl-;473332-52-4;DTXSID70476091

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Stannane, [2,6-bis(methoxymethyl)phenyl]triphenyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:8
Exact Mass:516.111133
Heavy Atom Count:31
Complexity:446

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COCC1=C(C(=CC=C1)COC)[Sn](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of Stannane, [2,6-bis(methoxymethyl)phenyl]triphenyl-

There total 2 articles about Stannane, [2,6-bis(methoxymethyl)phenyl]triphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 65654-53-7
1-bromo-2,6-bis(methoxymethyl)benzene

: 639-58-7
triphenyltin chloride

: 473332-52-4
[2,6-bis(methoxymethyl)phenyl](triphenyl)tin

Guidance literature:: With nBuLi; In diethyl ether; hexane; nBuLi was added to stirred soln. of ligand in Et2O at -78°C, stirred for 2 h, added dropwise to hexane soln. of Sn-compound at -78°C, stirred for 2 h under Ar; solvent was evapd. in vacuo, dissolved in CHCl3, filtered, concd., layered with pentane, crystd.; elem. anal.;
DOI:10.1021/om020361i

Reference yield: 45.0%

: 2,6-(MeOCH₂)2C₆H₃Al(i-Bu)2

: 76-87-9
triphenyltin(IV) hydroxide

: 473332-52-4
[2,6-bis(methoxymethyl)phenyl](triphenyl)tin

: (CH₃)2CHCH₂^(1-)*Al⁽³⁺⁾*O^(2-)=(CH₃)2CHCH₂AlO

Guidance literature:: In hexane; byproducts: C4H10; (Ar); std. Schlenk technique; Ph3SnOH (1 equiv.) was added to soln. of Al compd. (1 equiv.) in hexane; suspn. was stirred at room temp. for 24 h; exposed to air for 12 h; filtered; evapd. (vac.); elem. anal.;
DOI:10.1016/j.jorganchem.2005.08.043

Reference yield: 80.0%

: 473332-52-4
[2,6-bis(methoxymethyl)phenyl](triphenyl)tin

: 437-17-2
tritylium hexafluorophosphate

: 794537-54-5
[2,6-bis(methoxymethyl)phenyl]diphenyltin hexafluorophosphate

Guidance literature:: In toluene; (Ar); standard Schlenk technique; Ph3CPF6 was added to stirred soln. of Sn compd. in toluene; suspn. was stirred at 25°C for 2 d; filtered; washed (CHCl3); elem. anal.;
DOI:10.1021/om049636f