Cyclohexanone, 3-(2-methylphenyl)-, (3S)-

Base Information

Chemical Name:Cyclohexanone, 3-(2-methylphenyl)-, (3S)-
CAS No.:475599-60-1
Molecular Formula:C13H16O
Molecular Weight:188.269
Hs Code.:
Mol file:475599-60-1.mol

Synonyms:

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Chemical Property of Cyclohexanone, 3-(2-methylphenyl)-, (3S)-

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Technology Process of Cyclohexanone, 3-(2-methylphenyl)-, (3S)-

There total 10 articles about Cyclohexanone, 3-(2-methylphenyl)-, (3S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 930-68-7
cyclohexenone

: 16419-60-6
2-Methylphenylboronic acid

: 475599-60-1
(S)-3-(2-methylphenyl)-cyclohexanone

Guidance literature:: With chlorobis(ethylene)rhodium(I) dimer; (R)-(+)-[(η⁵-1-bis(3,5-dimethylphenyl)phosphino-2-(3-diphenylphosphino-2-methylpropenyl)cyclopentadienyl-P)]manganese(I) dicarbonyl; potassium hydroxide; In 1,4-dioxane; water; at 50 ℃; for 7h; enantioselective reaction; Inert atmosphere;
DOI:10.1021/jacs.6b11243

Reference yield: 99.0%

: 475599-60-1
(S)-3-(2-methylphenyl)-cyclohexanone

Guidance literature:: With chlorobis(ethylene)rhodium(I) dimer; ((η⁵-1-bis-(3,5-dimethylphenyl)phosphino-2-(3-diphenylphosphino-2-methylpropenyl)cyclopentadienyl-p))manganese(I) dicarbonyl; potassium hydroxide; In 1,4-dioxane; at 20 - 50 ℃; for 10h; Inert atmosphere;

Reference yield: 90.0%

: 930-68-7
cyclohexenone

: 363-86-0
trifluoro(2-tolyl)silane

: 475599-60-1
(S)-3-(2-methylphenyl)-cyclohexanone

Guidance literature:: trifluoro(2-tolyl)silane; With tris(dimethylamino)sulfonium trimethylsilyldifluoride; In dichloromethane; for 0.0833333h; Inert atmosphere;

cyclohexenone; With C₄₁H₄₂BrCuN₂; In dichloromethane; at 40 ℃; for 40h; Inert atmosphere;

With hydrogenchloride; water; In dichloromethane; optical yield given as %ee; enantioselective reaction;
DOI:10.1021/jo900589x