cis-caronaldehydic acid hemiacetal

Base Information

• Chemical Name: cis-caronaldehydic acid hemiacetal
• CAS No.: 26771-21-1
• Molecular Formula: C7H10 O3
• Molecular Weight: 142.155
• Hs Code.: 2932209090
• Mol file: 26771-21-1.mol

Synonyms:Cyclopropanecarboxylicacid, 3-(dihydroxymethyl)-2,2-dimethyl-, g-lactone (7CI)

Chemical Property of cis-caronaldehydic acid hemiacetal

Chemical Property:

• Vapor Pressure: 0.000193mmHg at 25°C
• Boiling Point: 292.6°C at 760 mmHg
• Flash Point: 135.8°C
• PSA: 46.53000
• Density: 1.287g/cm³
• LogP: 0.13380

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of cis-caronaldehydic acid hemiacetal

There total 5 articles about cis-caronaldehydic acid hemiacetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

methanol (67-56-1) + C22H24O7 (1381843-47-5) → C14H18O5 + (1R,4R,5S)-(+)-4-hydroxy-6,6-dimethyl-3-oxabicyclo<3.1.0>hexan-2-one (2102-46-7,26771-21-1,67528-54-5,72937-63-4,79026-47-4,79082-71-6,99297-25-3,73611-02-6) + (1R,5S,6S,7S)-6-benzoyloxymethyl-7-hydroxy-2-oxabicyclo<3.2.0>octan-3-one + (1R,4R,5S)-4-Methoxy-6,6-dimethyl-3-oxa-bicyclo[3.1.0]hexan-2-one

Guidance literature:

With pyridinium p-toluenesulfonate; at 60 ℃; for 1h;

DOI:10.1016/j.mencom.2012.05.002

Reference yield: 85.0%

methanol (67-56-1) + C22H24O7 (1381843-39-5) → C14H18O5 + C15H16O5 (69793-37-9) + (1R,4R,5S)-(+)-4-hydroxy-6,6-dimethyl-3-oxabicyclo<3.1.0>hexan-2-one (2102-46-7,26771-21-1,67528-54-5,72937-63-4,79026-47-4,79082-71-6,99297-25-3,73611-02-6) + (1R,4R,5S)-4-Methoxy-6,6-dimethyl-3-oxa-bicyclo[3.1.0]hexan-2-one

Guidance literature:

With pyridinium p-toluenesulfonate; at 60 ℃; for 1h;

DOI:10.1016/j.mencom.2012.05.002

Reference yield: 68.0%

methanol (67-56-1) + C21H34O6Si (1381843-06-6) → C14H18O5 + (1R,4R,5S)-(+)-4-hydroxy-6,6-dimethyl-3-oxabicyclo<3.1.0>hexan-2-one (2102-46-7,26771-21-1,67528-54-5,72937-63-4,79026-47-4,79082-71-6,99297-25-3,73611-02-6) + (3aR,4S,5R,6aS)-4-((tert-butyldimethylsilyloxy)methyl)-5-hydroxyhexahydro-2H-cyclopenta[b]furan-2-one (58707-50-9,72777-85-6,81203-78-3,65025-94-7) + (1R,4R,5S)-4-Methoxy-6,6-dimethyl-3-oxa-bicyclo[3.1.0]hexan-2-one

Guidance literature:

With pyridinium p-toluenesulfonate; at 60 ℃; for 1h;

DOI:10.1016/j.mencom.2012.05.002

upstream raw materials:

C₉H₁₂O₅

methanol

C₂₁H₃₄O₆Si

C₂₂H₂₄O₇

Downstream raw materials:

(1R,5S) 6,6-dimethyl-4(R)-[(1'S), (2'R), (5'S) 2'-isopropyl-5'-methyl-cyclohexanoxy]-3-oxabicyclo-(3,1,0)-hexan-2-one

C₂₂H₂₄O₇

C₂₂H₂₄O₇

C₂₂H₂₄O₇

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 26771-21-1 cis-caronaldehydic acid hemiacetal

Send

Send

Metric Ton KG G Pound L ML

Send

Send