Nickel acetate

Base Information

• Chemical Name: Nickel acetate
• CAS No.: 14998-37-9
• Deprecated CAS: 17593-69-0,219782-27-1
• Molecular Formula: 2C₂H₃O₂*Ni
• Molecular Weight: 176.779
• European Community (EC) Number: 206-761-7,239-086-1
• UN Number: 2811,3077
• UNII: 99QP4ELX96
• DSSTox Substance ID: DTXSID7020926
• Nikkaji Number: J5.712F
• Wikipedia: Nickel(II)_acetate
• Wikidata: Q899422
• NCI Thesaurus Code: C45867
• Mol file: 14998-37-9.mol

Synonyms:nickel (II) acetate;nickel acetate;nickelous acetate

Chemical Property of Nickel acetate

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 175.961950
• Heavy Atom Count: 9
• Complexity: 25.5
• Transport DOT Label: Poison

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Nickel Compounds, Inorganic
• Canonical SMILES: CC(=O)[O-].CC(=O)[O-].[Ni+2]

Technology Process of Nickel acetate

There total 30 articles about Nickel acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

nickel(II) carbonate (719261-06-0) + acetic acid (64-19-7,77671-22-8) → nickel diacetate (373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6)

Guidance literature:

at 85 ℃; for 0.766667h; pH=3.4; pH-value; Temperature;

Reference yield: 71.0%

((C6H5)3P)2Ni(CdGe(C6H5)3)Ge(C6H5)3 → triphenylgermane (2816-43-5) + nickel diacetate (373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6) + cadmium(II) acetate (543-90-8)

Guidance literature:

With acetic acid; In toluene; byproducts: P(C6H5)3; mixt. keeping for 4 h at 80°C in argon atmosphere or in evac. sealed ampul; ppt. (Cd- and Ni-acetate) washing (toluene) and drying; GLC anal.;

Reference yield: 69.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + Allyl acetate (591-87-7) → bis(η3-allyl)nickel(II) + nickel diacetate (373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6)

Guidance literature:

In diethyl ether; under N2 or argon or under vac., soln. of org. compd. added to Ni(cod)2(1/1 mol ratio) at -78°C, stirred at 10°C for 2 h; cooled to -78°C, solvent evapd. under vac., warmed to 0°C, product distd., distn. residue identified as Ni-acetate; detn. by IR, NMR spect.;

DOI:10.1021/ja00413a014

upstream raw materials:

acetic anhydride

nickel diacetate

acetic acid

bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

Downstream raw materials:

N-acetyl-D-mannosamine

2-acetamido-2-deoxy-D-glucose

octane

nickel(III) acetate