Methyl butyl carbonate

Base Information

• Chemical Name: Methyl butyl carbonate
• CAS No.: 4824-75-3
• Molecular Formula: C6H12O3
• Molecular Weight: 132.159
• Mol file: 4824-75-3.mol

Synonyms:Carbonic acid,butyl methyl ester;carbonic acid butyl ester-methyl ester;Kohlensaeure-butylester-methylester;methyl n-butyl carbonate;Methyl-butyl-carbonat;1-butyl methylcarbonate;METHYL BUTYL CARBONATE;

Chemical Property of Methyl butyl carbonate

Chemical Property:

• Boiling Point: 150.5 °C(Press: 745 Torr)
• PSA: 35.53000
• Density: 0.961±0.06 g/cm3(Predicted)
• LogP: 1.56950

Purity/Quality:

99%, ^*data from raw suppliers

butylmethylcarbonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methyl butyl carbonate

There total 2 articles about Methyl butyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.5%

methyl N-hydroxycarbamate (584-07-6) + butan-1-ol (71-36-3) → n-butyl methyl carbonate (4824-75-3) + carbonic acid dimethyl ester (616-38-6)

Guidance literature:

With lead dioxide; In dichloromethane; at 40 ℃; for 0.166667h;

DOI:10.1135/cccc19961053

Reference yield:

carbonic acid dimethyl ester (616-38-6) + butan-1-ol (71-36-3) → n-butyl methyl carbonate (4824-75-3) + Dibutyl carbonate (542-52-9)

Guidance literature:

at 80 ℃; for 4h; Temperature; Catalytic behavior; Autoclave;

DOI:10.1016/j.molcata.2014.11.022

Reference yield:

n-butyl methyl carbonate (4824-75-3) + phenol (108-95-2,27073-41-2) → n-butyl phenyl ether (1126-79-0) + methoxybenzene (100-66-3)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 120 ℃; for 15h; Title compound not separated from byproducts;

DOI:10.1055/s-2000-6488

upstream raw materials:

methyl N-hydroxycarbamate

butan-1-ol

carbonic acid dimethyl ester

Downstream raw materials:

n-butyl phenyl ether

methoxybenzene

methanol

1-butylene

Refernces

• 1、 Mindl, Jaromir,Halama, Ales,Cernosek, Zdenek. "Alkoxycarbonylation of alcohols and phenols by nitrosoformates". . p. 1053 - 1063. Retrieved 2007/10/03.