Distannoxane, hexakis[(2-chlorophenyl)methyl]-

Base Information

• Chemical Name: Distannoxane, hexakis[(2-chlorophenyl)methyl]-
• CAS No.: 491879-81-3
• Molecular Formula: C₄₂H₃₆Cl₆OSn₂
• Molecular Weight: 1006.89
• Mol file: 491879-81-3.mol

Synonyms:

Chemical Property of Distannoxane, hexakis[(2-chlorophenyl)methyl]-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Distannoxane, hexakis[(2-chlorophenyl)methyl]-

There total 1 articles about Distannoxane, hexakis[(2-chlorophenyl)methyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-chlorobenzylmagnesium bromide (56812-59-0) + stannic bromide (7789-67-5) → [(2-Cl-C6H4CH2)3Sn]2O (491879-81-3) + Sn(o-chloro-benzyl)4

Guidance literature:

In diethyl ether;

Reference yield: 78.5%

quinoline-2-carboxylic acid (93-10-7,1199266-78-8) + [(2-Cl-C6H4CH2)3Sn]2O (491879-81-3) + dichloromethane (75-09-2) → (ClC6H4CH2)2Sn(C9H6NCOO)2*CH2Cl2

Guidance literature:

In benzene; to a stirred soln. of 2-quinaldic acid in benzene was added Sn-compound,the mixt. was heated under reflux for 6-7 h; the solvent was removed by evapn. in vac., recrystd. from CH2Cl2 and n-hexane; elem. anal.;

DOI:10.1016/j.jorganchem.2005.03.046

Reference yield: 69.0%

Pyridine-2,5-dicarboxylic acid (100-26-5) + [(2-Cl-C6H4CH2)3Sn]2O (491879-81-3) → ((2-Cl-C6H4CH2)3Sn)2(2,5-pyridinedicarboxylate) (942499-50-5)

Guidance literature:

In methanol; benzene; stoich., ligand and Sn compound in 5:1 solvent mixt. of C6H6 and CH3OH refluxed for 8 h; cooled to room temp., evapd.(vac.), recrystd.(CH3OH), elem. anal.;

DOI:10.1016/j.ica.2006.12.012

upstream raw materials:

2-chlorobenzylmagnesium bromide

stannic bromide

Downstream raw materials:

((2-Cl-C₆H₄CH₂)3Sn)2(2,5-pyridinedicarboxylate)