2,6-Dimethylbenzyl alcohol

Base Information

• Chemical Name: 2,6-Dimethylbenzyl alcohol
• CAS No.: 62285-58-9
• Molecular Formula: C9H12O
• Molecular Weight: 136.194
• Hs Code.: 29062990
• Mol file: 62285-58-9.mol

Synonyms:Benzylalcohol, 2,6-dimethyl- (7CI);(2,6-Dimethylphenyl)methanol;2,6-Dimethylbenzylalcohol;NSC 618295;

Chemical Property of 2,6-Dimethylbenzyl alcohol

Chemical Property:

• Vapor Pressure: 0.0479mmHg at 25°C
• Melting Point: 81-82 °C(Solv: ligroine (8032-32-4))
• Refractive Index: 1.536
• Boiling Point: 225.9 °C at 760 mmHg
• PKA: 14.38±0.10(Predicted)
• Flash Point: 101.7 °C
• PSA: 20.23000
• Density: 1.002 g/cm³
• LogP: 1.79570
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

98%,99%, ^*data from raw suppliers

(2,6-Dimethylphenyl)methanol ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,6-Dimethylbenzyl alcohol

There total 17 articles about 2,6-Dimethylbenzyl alcohol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2,6-dimethylbenzoic acid (632-46-2) → 2,6-dimethylbenzyl alcohol (62285-58-9)

Guidance literature:

With Trimethyl borate; dimethylsulfide borane complex; In tetrahydrofuran; for 72h; Ambient temperature;

DOI:10.1016/S0968-0896(96)00230-1

Reference yield: 99.0%

→ 2,6-dimethylbenzyl alcohol (62285-58-9)

Guidance literature:

With bis(1,5-cyclooctadiene)diiridium(I) dichloride; ethanol; hydrogen; C₃₁H₃₀FeNOP; isopropyl alcohol; lithium tert-butoxide; at 20 ℃; for 12h; under 750.075 Torr;

Reference yield: 91.0%

2,6-dimethylbenzaldehyde (1123-56-4) → 2,6-dimethylbenzyl alcohol (62285-58-9)

Guidance literature:

2,6-dimethylbenzaldehyde; With (dppe)2Fe(H)2*(C₇H₈)2; Na-tetrakis(ethoxy)borate; In toluene; at 100 ℃; for 1h; visible light irradiation; Inert atmosphere;

With water; sodium hydroxide; In methanol; toluene; at 20 ℃; for 16h;

DOI:10.1002/adsc.201000676

upstream raw materials:

2,6-dimethylbenzoic acid

formaldehyd

2-Bromo-m-xylene

methyl 2,6-dimethylbenzoate

Downstream raw materials:

2,6-dimethylbenzyl chloride

2,6-dimethylbenzaldehyde

2-(2,6-di-methylbenzyl)isoindoline-1,3-dione

6-bromo-8-([(2,6-dimethylphenyl)methyl]oxy)-2,3-dimethylimidazo[1,2-a]pyridine

Refernces

• 1、 -. "PROCESS FOR PREPARING 2,6-DIALKYLPHENYLACETIC ACIDS". Paragraph 0220-0222. . Retrieved 2022/01/04.
• 2、 Bhunia, Mrinal,Sahoo, Sumeet Ranjan,Shaw, Bikash Kumar,Vaidya, Shefali,Pariyar, Anand,Vijaykumar, Gonela,Adhikari, Debashis,Mandal, Swadhin K.. "Storing redox equivalent in the phenalenyl backbone towards catalytic multi-electron reduction". . p. 7433 - 7441. Retrieved 2019/08/15.