2-MeO-BDE-123

Base Information

Chemical Name:2-MeO-BDE-123
CAS No.:497106-84-0
Molecular Formula:C13H7Br5O2
Molecular Weight:594.717
Hs Code.:
DSSTox Substance ID:DTXSID701339500
Nikkaji Number:J2.010.487B

Synonyms:2-MeO-BDE-123;DTXSID701339500;1,2,3-Tribromo-5-(2,4-dibromophenoxy)-4-methoxybenzene;497106-84-0

Suppliers and Price of 2-MeO-BDE-123

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of 2-MeO-BDE-123

Chemical Property:

XLogP3:6.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:593.63219
Heavy Atom Count:20
Complexity:319

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=C(C(=C(C=C1OC2=C(C=C(C=C2)Br)Br)Br)Br)Br

Technology Process of 2-MeO-BDE-123

There total 4 articles about 2-MeO-BDE-123 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 80246-24-8
2'-hydroxy-2,3',4,4',5'-pentabromodiphenyl ether

: 74-88-4
methyl iodide

: 497106-84-0
2'-methoxy-2,3',4,4',5'-pentabromodiphenyl ether

Guidance literature:: With sodium hydroxide; tetra(n-butyl)ammonium hydroxide; In dichloromethane; water; at 20 ℃; for 5h;
DOI:10.1002/ejoc.200300081

Reference yield:

: 4656-58-0
2′-hydroxy-2,4,4′-tribromodiphenyl ether

: 497106-84-0
2'-methoxy-2,3',4,4',5'-pentabromodiphenyl ether

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / benzyltrimethylammonium tribromide; calcium carbonate / CH₂Cl₂; methanol / 20 °C

2: 98 percent / NaOH; tetrabutylammonium hydroxide / CH₂Cl₂; H₂O / 5 h / 20 °C

With sodium hydroxide; benzyltrimethylammonium tribromide; tetra(n-butyl)ammonium hydroxide; calcium carbonate; In methanol; dichloromethane; water;
DOI:10.1002/ejoc.200300081

Reference yield:

: 93777-26-5
5-bromo-2-fluorobenzaldehyde

: 497106-84-0
2'-methoxy-2,3',4,4',5'-pentabromodiphenyl ether

Guidance literature:: Multi-step reaction with 4 steps

1.1: 85 percent / Na₂CO₃ / N,N-dimethyl-acetamide / 1 h / Heating

2.1: KH₂PO₄; CF₃CO₃H / CH₂Cl₂ / 1.5 h / 0 °C

2.2: 99 percent / hydrochloric acid / methanol / 15 h

3.1: 97 percent / benzyltrimethylammonium tribromide; calcium carbonate / CH₂Cl₂; methanol / 20 °C

4.1: 98 percent / NaOH; tetrabutylammonium hydroxide / CH₂Cl₂; H₂O / 5 h / 20 °C

With sodium hydroxide; potassium dihydrogenphosphate; benzyltrimethylammonium tribromide; trifluoroacetyl peroxide; tetra(n-butyl)ammonium hydroxide; sodium carbonate; calcium carbonate; In methanol; dichloromethane; N,N-dimethyl acetamide; water; 2.1: Baeyer-Villiger oxidation;
DOI:10.1002/ejoc.200300081