2-sulfanylacetohydrazide

Base Information

• Chemical Name: 2-sulfanylacetohydrazide
• CAS No.: 760-30-5
• Molecular Formula: C2H6 N2 O S
• Molecular Weight: 106.148
• Hs Code.: 2930909899
• Mol file: 760-30-5.mol

Synonyms:Aceticacid, mercapto-, hydrazide (6CI,7CI,8CI,9CI); Mercaptoacetic acid hydrazide

Chemical Property of 2-sulfanylacetohydrazide

Chemical Property:

• Vapor Pressure: 0.000112mmHg at 25°C
• Boiling Point: 336.5°C at 760 mmHg
• Flash Point: 157.3°C
• PSA: 97.41000
• Density: 1.245g/cm³
• LogP: 0.44670

Purity/Quality:

99% ^*data from raw suppliers

2-sulfanylacetohydrazide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-sulfanylacetohydrazide

There total 2 articles about 2-sulfanylacetohydrazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

ethyl 2-sulfanylacetate (623-51-8) → 2-mercaptoacetohydrazide (760-30-5)

Guidance literature:

With hydrazine hydrate; In ethanol; Reflux;

DOI:10.1016/j.bmc.2011.03.021

Reference yield:

Methyl thioglycolate (2365-48-2) → 2-mercaptoacetohydrazide (760-30-5)

Guidance literature:

With hydrazine; In methanol; Heating;

DOI:10.1021/jo00422a034

Reference yield: 75.0%

2-mercaptoacetohydrazide (760-30-5) + Dithiophosphoric acid S-chlorocarbonylmethyl ester O,O'-dipropyl ester → 2,2′-disulfanediyldi(acetohydrazide) (6854-84-8) + (Dipropoxy-thiophosphorylsulfanyl)-thioacetic acid S-hydrazinocarbonylmethyl ester + Dithiophosphoric acid S-(2-{N'-[2-(dipropoxy-thiophosphorylsulfanyl)-acetyl]-hydrazino}-2-oxo-ethyl) ester O,O'-dipropyl ester + (Dipropoxy-thiophosphorylsulfanyl)-acetic acid; compound with hydrazinocarbonylmethyldisulfanyl-acetic acid hydrazide

Guidance literature:

With triethylamine; In 1,4-dioxane; at 50 ℃;

upstream raw materials:

ethyl 2-sulfanylacetate

Methyl thioglycolate

Downstream raw materials:

2,2′-disulfanediyldi(acetohydrazide)

Mercapto-acetic acid [1-(2-chloro-phenyl)-eth-(E)-ylidene]-hydrazide