Cyclohexanone, 2,3-dimethyl-6-(1-methylethylidene)-, (3R)-

Base Information

Chemical Name:Cyclohexanone, 2,3-dimethyl-6-(1-methylethylidene)-, (3R)-
CAS No.:501369-28-4
Molecular Formula:C11H18O
Molecular Weight:166.263
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Cyclohexanone, 2,3-dimethyl-6-(1-methylethylidene)-, (3R)-

Chemical Property:

Purity/Quality:

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Technology Process of Cyclohexanone, 2,3-dimethyl-6-(1-methylethylidene)-, (3R)-

There total 1 articles about Cyclohexanone, 2,3-dimethyl-6-(1-methylethylidene)-, (3R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 89-82-7,90449-51-7
pulegone

: 74-88-4
methyl iodide

: 501369-28-4
(R)-6-Isopropylidene-2,3-dimethyl-cyclohexanone

Guidance literature:: With lithium chloride; lithium diisopropyl amide;
DOI:10.1021/ja0296531

Reference yield: 75.0%

: 501369-28-4
(R)-6-Isopropylidene-2,3-dimethyl-cyclohexanone

: 234078-11-6
(2RS,3R)-2,3-dimethylcyclohexanone

Guidance literature:: With potassium hydroxide; Heating;
DOI:10.1021/ja0296531

Reference yield:

: 501369-28-4
(R)-6-Isopropylidene-2,3-dimethyl-cyclohexanone

: (1S,4S,5R)-3-Methoxymethoxymethyl-4,5-dimethyl-4-vinyl-cyclohex-2-enol

Guidance literature:: Multi-step reaction with 8 steps

1.1: 75 percent / KOH / Heating

2.1: diisopropyl amine; n-butyllithium; triethylamine / chlorotrimethylsilane / tetrahydrofuran; petroleum ether / -78 - 0 °C

2.2: bromine / tetrahydrofuran; petroleum ether / 2 h / -78 °C

3.1: 5.0 g / lithium carbonate; lithium bromide / dimethylformamide / 4 h / 100 - 105 °C

4.1: diisopropyl amine; n-butyllithium / diethyl ether; petroleum ether / 0.58 h / -78 °C

4.2: diethyl ether; petroleum ether / 1 h / -78 °C

5.1: 378 mg / triethylamine; methanesulfonyl chloride / CH₂Cl₂ / 4 h / 20 °C

6.1: lithium chloride / tetrahydrofuran / 2 h / 20 °C

6.2: n-butyllithium / tetrahydrofuran; petroleum ether / 0.08 h / -78 °C

6.3: 70 percent / tetrahydrofuran; petroleum ether / 0.5 h / -78 °C

7.1: 91 percent / PCC / CH₂Cl₂ / 48 h / 20 °C

8.1: cerium trichloride; sodium borohydride / methanol / 0.5 h / 0 °C

With potassium hydroxide; sodium tetrahydroborate; n-butyllithium; cerium(III) chloride; lithium carbonate; methanesulfonyl chloride; triethylamine; diisopropylamine; pyridinium chlorochromate; lithium chloride; lithium bromide; chloro-trimethyl-silane; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide; Petroleum ether;
DOI:10.1021/ja0296531