Benzenecarboximidamide, N,N-diethyl-

Base Information

• Chemical Name: Benzenecarboximidamide, N,N-diethyl-
• CAS No.: 50458-37-2
• Molecular Formula: C11H16N2
• Molecular Weight: 176.261
• Mol file: 50458-37-2.mol

Synonyms:

Chemical Property of Benzenecarboximidamide, N,N-diethyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzenecarboximidamide, N,N-diethyl-

There total 6 articles about Benzenecarboximidamide, N,N-diethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

diethylamine (109-89-7) + N-methyl-N-phenylbenzimidamide (57767-07-4) → N,N-diethylbenzamidine (50458-37-2)

Guidance literature:

With bis(trimethylsilyl)amide yttrium(III); In neat (no solvent); at 60 ℃; for 24h;

DOI:10.1039/c8cy01481g

Reference yield:

benzimidic acid ethyl ester (825-60-5) → N,N-diethylbenzamidine (50458-37-2) + 2,4,6-triphenyl-1,3,5-triazine (493-77-6)

Guidance literature:

With ethanol; at 50 ℃; Behandeln des Reaktionsprodukts mit wss. Natronlauge;

Reference yield:

benzonitrile (100-47-0) + diethylamine (109-89-7) → N,N-diethylbenzamidine (50458-37-2)

Guidance literature:

upstream raw materials:

benzonitrile

diethylamine

methylmagnesium bromide

benzimidic acid ethyl ester

Downstream raw materials:

N'-(tert-butyl-thiocarbamoyl)-N,N-diethyl-benzamidine

benzyl-(5-nitro-4-phenyl-thiazol-2-yl)-amine

N,N-diethyl-N′-(phenylcarbamothioyl)benzimidamide

N′-((4-chlorophenyl)carbamothioyl)-N,N-diethylbenzimidamide

Refernces

• 1、 Zhang, Dexing,Liu, Ruiting,Zhou, Xigeng. "Intramolecular alkene hydroamination and degradation of amidines: Divergent behavior of rare earth metal amidinate intermediates". . p. 5573 - 5581. Retrieved 2018/11/20.