Bis(cyano-C)bis(1,10-phenanthroline-N1,N10)iron

Base Information

• Chemical Name: Bis(cyano-C)bis(1,10-phenanthroline-N1,N10)iron
• CAS No.: 14768-11-7
• Molecular Formula: C₂₆H₁₆FeN₆
• Molecular Weight: 468.3
• European Community (EC) Number: 238-833-9
• Mol file: 14768-11-7.mol

Synonyms:EINECS 238-833-9;Bis(cyano-C)bis(1,10-phenanthroline-N1,N10)iron;14768-11-7;C26H16FeN6;Iron, bis(cyano-.kappa.C)bis(1,10-phenanthroline-.kappa.N1,.kappa.N10)-;C26-H16-Fe-N6;Iron, bis(cyano-C)bis(1,10-phenanthroline-N1,N10)-;PENTADECANOICACID

Chemical Property of Bis(cyano-C)bis(1,10-phenanthroline-N1,N10)iron

Chemical Property:

• Vapor Pressure: 3.38E-05mmHg at 25°C
• Boiling Point: 365.1 °C at 760 mmHg
• Flash Point: 164.8 °C
• PSA: 99.14000
• LogP: 5.59706
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 468.078580
• Heavy Atom Count: 33
• Complexity: 193

Purity/Quality:

99% ^*data from raw suppliers

FERROCYPHEN 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 25
• Safety Statements: 36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C-]#N.[C-]#N.C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.[Fe+2]

Technology Process of Bis(cyano-C)bis(1,10-phenanthroline-N1,N10)iron

There total 5 articles about Bis(cyano-C)bis(1,10-phenanthroline-N1,N10)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

ferroin (14634-91-4) → dicyanobis(1,10-phenanthroline)iron(II) (14768-11-7,30872-77-6,80875-80-5,15334-30-2,15362-08-0)

Guidance literature:

With potassium cyanide; In water; Fe salt aq. soln. heating nearly boiling, aq. KCN adding at once, stirring, cooling to room temp., dark violet crystals collecting, drying in vacuo; identified by IR, UV spectra;

DOI:10.1021/om00065a010

Reference yield:

1,10-Phenanthroline (66-71-7) + pentacyanoaquaferrate(II) → ferroin (47836-89-5,14708-99-7,24324-38-7) + [Fe(1,10-phenanthroline)(CN)4](2-) (17455-55-9) + dicyanobis(1,10-phenanthroline)iron(II) (14768-11-7,30872-77-6,80875-80-5,15334-30-2,15362-08-0)

Guidance literature:

With sodium chloride; ascorbic acid; In water; Irradiation (UV/VIS); decompn. of aq. soln. of iron complex in the presence of o-phenanthroline (20-45°C, addn. of ascorbic acid, NaCl) under UV-irradiation; UV spect.; Kinetics;

DOI:10.1016/S0020-1693(00)87916-5

Reference yield:

1,10-Phenanthroline (66-71-7) + iron (7439-89-6) → dicyanobis(1,10-phenanthroline)iron(II) (14768-11-7,30872-77-6,80875-80-5,15334-30-2,15362-08-0)

Guidance literature:

With potassium cyanide; In methanol; water; Electrochem. Process; electrochem. oxidn. of Fe wire in MeOH-H2O (2:1) in presence of KCN andC12H8N2 (1:1 mol ratio);

upstream raw materials:

ferroin

cyanide^(1-)

ferroin

1,10-Phenanthroline

Refernces

• 1、 Blandamer, Michael J.,Burgess, John,Clark, Barbara. "Enhancement of Rates of Reaction using Neutral Water/Organic Microemulsions as Solvent Media". . p. 659 - 660. Retrieved 2007/10/02.
• 2、 Rollick,Kochi. "Ligand effects on the reduction of iron(III) complexes by alkyl radicals. Formation of alkyl isocyanides and chlorides from cyanoiron(III) and chloroiron(III) species". . p. 725 - 732. Retrieved 2008/10/08.