Ferroin

Base Information

• Chemical Name: Ferroin
• CAS No.: 14634-91-4
• Molecular Formula: C36H24FeN6O4S
• Molecular Weight: 692.537
• Hs Code.: 29319090
• European Community (EC) Number: 238-676-6
• UNII: YP88WTW2E4
• DSSTox Substance ID: DTXSID8065799
• Wikipedia: Ferroin
• Mol file: 14634-91-4.mol

Synonyms:0-phenanthroline;ferroin;ferroin diperchlorate;ferroin sulfate (1:1);iron(II) 1,10-phenanthroline;ortho-phenanthroline

Chemical Property of Ferroin

Chemical Property:

• Appearance/Colour: dark red liquid
• Boiling Point: 365.1°Cat760mmHg
• Flash Point: 164.8°C
• PSA: 165.98000
• Density: g/cm³
• LogP: 8.08930
• Storage Temp.: Amber Vial, Refrigerator, Under inert atmosphere
• Solubility.: Water
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 0
• Exact Mass: 692.092910
• Heavy Atom Count: 48
• Complexity: 245

Purity/Quality:

98%,99%, ^*data from raw suppliers

Ferroin Sulfate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): N
• Hazard Codes: N
• Statements: 52/53-51/53
• Safety Statements: 24/25-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Organic Compounds, Metal Salts
• Canonical SMILES: C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.[O-]S(=O)(=O)[O-].[Fe+2]
• Uses: Ferroin Sulfate, tech. is a metal catalyst used prominently in dye synthesis which has a green oxidative degradation. Dyes and metabolites.

Technology Process of Ferroin

There total 6 articles about Ferroin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ferrous(II) sulfate heptahydrate + 1,10-Phenanthroline (66-71-7) → ferroin (14634-91-4)

Guidance literature:

In water; FeSO4 and phenanthroline reacted in a 1:3 stoichiometric relationship;

DOI:10.1021/jp0456279

Reference yield:

1,10-Phenanthroline (66-71-7) + iron(II) sulfate → ferroin (14634-91-4)

Guidance literature:

FeS:1,10-phenanthroline, molar ratio 1:3;

DOI:10.1063/1.469732

Reference yield:

tris(1,10-phenanthroline)iron(II) perchlorate (14586-54-0) → ferroin (14634-91-4)

Guidance literature:

With Na₂SO₄; In water; addn of pptd. educt to water contg. anion exchange resin (equilibrated with Na2SO4); not isolated, spectrophotometric control;

DOI:10.1039/f19888404261

upstream raw materials:

1,10-Phenanthroline

iron(II)

tris(1,10-phenanthroline)iron(II) perchlorate

Downstream raw materials:

dicyanobis(1,10-phenanthroline)iron(II)

Refernces

• 1、 Toth, Agota,Showalter, Kenneth. "Logic gates in excitable media". . p. 2058 - 2066. Retrieved 1995.
• 2、 Wang, Jichang,Zhao, Jinpei,Chen, Yu,Gao, Qingyu,Wang, Yumei. "Coexistence of two bifurcation regimes in a closed ferroin-catalyzed Belousov-Zhabotinsky reaction". . p. 1374 - 1381. Retrieved 2005.
• 3、 Harati, Mohammad. "Chemical wave in the un-illuminated aminophenol-bromate beads system". . p. 126 - 129. Retrieved 2009.
• 4、 Plesser, Theo,Mueller, Stefan C.,Hess, Benno. "Spiral Wave Dynamics as a Function of Proton Concentration in the Ferroin-Catalyzed Belousov-Zhabotinskii Reaction". . p. 7501 - 7507. Retrieved 1990.
• 5、 Singh, Nanhai,Prasad, Lal Bahadur. "Preparation, spectroscopic characterization and solid state electrical conductance of bimetallic salts of the type [M(L-L)3][M'(MNT)2] . Part II". . p. 627 - 646. Retrieved 1996.
• 6、 Du, Zhongyu,Duan, Siyu,Ma, Mingfang,Xu, Xiangyu,Li, Zhenquan,Kong, Lingdong,Liu, Jun. "Kinetics of two redox reactions in 2-butoxyethanol and water near its critical point of solution". . p. 258 - 265. Retrieved 2019/02/01.