methyl 4-{[(4-methylphenyl)sulfonyl]oxy}benzoate

Base Information

Chemical Name:methyl 4-{[(4-methylphenyl)sulfonyl]oxy}benzoate
CAS No.:51207-43-3
Molecular Formula:C15H14O5S
Molecular Weight:306.339
Hs Code.:
Mol file:51207-43-3.mol

Synonyms:methyl 4-{[(4-methylphenyl)sulfonyl]oxy}benzoate;p-methoxycarbonylphenyl tosilate;p-Carbomethoxyphenyl p-toluenesulfonate;Methyl 4-(((4-methylphenyl)sulfonyl)oxy)benzoate;4-(methoxycarbonyl)phenyl tosylate;4-methyloxycarbonylphenyl tosylate;

Suppliers and Price of methyl 4-{[(4-methylphenyl)sulfonyl]oxy}benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of methyl 4-{[(4-methylphenyl)sulfonyl]oxy}benzoate

Chemical Property:

PSA：78.05000
LogP:3.63010

Purity/Quality:: 99.0%min. ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of methyl 4-{[(4-methylphenyl)sulfonyl]oxy}benzoate

There total 4 articles about methyl 4-{[(4-methylphenyl)sulfonyl]oxy}benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 99-76-3,156291-94-0
methyl 4-hydroxylbenzoate

: 98-59-9
p-toluenesulfonyl chloride

: 51207-43-3
methyl 4-(tosyloxy)benzoate

Guidance literature:: With dmap; triethylamine; In dichloromethane; for 2.25h; Inert atmosphere;
DOI:10.1039/c7cc06106d

Reference yield:

: 67-56-1
methanol

: C₃₂H₂₆O₅PS⁽¹⁺⁾*I^(1-)

: 51207-43-3
methyl 4-(tosyloxy)benzoate

Guidance literature:: C₃₂H₂₆O₅PS⁽¹⁺⁾*I^(1-); With zinc trifluoromethanesulfonate; In acetonitrile; at 60 ℃; for 0.5h; Inert atmosphere;

methanol; In acetonitrile; at 60 ℃; for 4h; Inert atmosphere;
DOI:10.1021/jo302502r

Reference yield:

: 51804-15-0
4-carboxyphenyl 4-methylbenzenesulfonate

: 51207-43-3
methyl 4-(tosyloxy)benzoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: iodine / acetonitrile / 0.17 h / Inert atmosphere

2.1: zinc trifluoromethanesulfonate / acetonitrile / 0.5 h / 60 °C / Inert atmosphere

2.2: 4 h / 60 °C / Inert atmosphere

With iodine; zinc trifluoromethanesulfonate; In acetonitrile;
DOI:10.1021/jo302502r