2-Undecenoic acid, ethyl ester, (2Z)-

Base Information

• Chemical Name: 2-Undecenoic acid, ethyl ester, (2Z)-
• CAS No.: 51577-38-9
• Molecular Formula: C13H24O2
• Molecular Weight: 212.332
• Mol file: 51577-38-9.mol

Synonyms:

Chemical Property of 2-Undecenoic acid, ethyl ester, (2Z)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-Undecenoic acid, ethyl ester, (2Z)-

There total 1 articles about 2-Undecenoic acid, ethyl ester, (2Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethanol (64-17-5) + carbon monoxide (201230-82-2) + cis-1-iodo-1-decene (66291-51-8) → ethyl undecanoate (627-90-7) + ethyl (Z)-2-undecenoate (51577-38-9) + (E)-undec-2-enoic acid ethyl ester (51577-37-8)

Guidance literature:

bis-triphenylphosphine-palladium(II) chloride; In various solvent(s); at 100 ℃; for 24h; under 22800 Torr;

DOI:10.1021/jo00013a050

Reference yield: 72.0%

(Z)-und (E)-2-Undecencarbonsaeureethylester (51577-37-8,78640-24-1,51577-38-9) → undecyl alcohol (112-42-5)

Guidance literature:

With dichloro(benzene)ruthenium(II) dimer; 2-((dicyclohexylphosphino)methyl)-1-methyl-1H-imidazolin; potassium tert-butylate; hydrogen; In tetrahydrofuran; at 120 ℃; for 16h; under 37503.8 Torr;

DOI:10.1002/chem.201200408

Reference yield:

(Z)-und (E)-2-Undecencarbonsaeureethylester (51577-37-8,78640-24-1,51577-38-9) → trans-2-undecen-1-ol (75039-83-7,75039-84-8,37617-03-1)

Guidance literature:

(Z)-und (E)-2-Undecencarbonsaeureethylester; With diethoxymethylane; zinc diacetate; In tetrahydrofuran; at 65 ℃; for 24h; Inert atmosphere;

With methanol; potassium hydroxide; chemoselective reaction;

DOI:10.1002/chem.201100800

upstream raw materials:

ethanol

carbon monoxide

cis-1-iodo-1-decene

Downstream raw materials:

trans-2-undecen-1-ol

undecyl alcohol