Diethyl (3-methylbut-2-en-1-yl)phosphonate

Base Information

Chemical Name:Diethyl (3-methylbut-2-en-1-yl)phosphonate
CAS No.:51795-72-3
Molecular Formula:C9H19O3P
Molecular Weight:206.21900
Hs Code.:
DSSTox Substance ID:DTXSID60455411
Nikkaji Number:J540.370G
Mol file:51795-72-3.mol

Synonyms:51795-72-3;Diethyl (3-methylbut-2-en-1-yl)phosphonate;SCHEMBL2458072;DTXSID60455411;diethyl 3-methyl-2-butenylphosphonate;AKOS024264221;3-Methyl-2-butenylphosphonic acid diethyl ester

Suppliers and Price of Diethyl (3-methylbut-2-en-1-yl)phosphonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Diethyl (3-methylbut-2-en-1-yl)phosphonate

Chemical Property:

PSA：45.34000
LogP:3.21870
XLogP3:1.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:6
Exact Mass:206.10718146
Heavy Atom Count:13
Complexity:197

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOP(=O)(CC=C(C)C)OCC

Technology Process of Diethyl (3-methylbut-2-en-1-yl)phosphonate

There total 3 articles about Diethyl (3-methylbut-2-en-1-yl)phosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 100-52-7
benzaldehyde

: (E)-diethyl 3-methylbuta-1,3-dienylphosphonate

: 51795-72-3
diethyl 3-methylbut-2-enylphosphonate

: 71071-55-1
diethyl (3-methyl-3-butenyl)phosphonate

: (±)-diethyl (3S,5S,E)-(5-hydroxy-3-methyl-5-phenyl)-pent-1-enyl phosphonate

Guidance literature:: (E)-diethyl 3-methylbuta-1,3-dienylphosphonate; With bis(acetylacetonate)nickel(II); In tetrahydrofuran; at 20 ℃; for 0.166667h; Inert atmosphere;

benzaldehyde; With triethyl borane; In tetrahydrofuran; at 20 ℃; for 36h; Inert atmosphere;
DOI:10.1021/acs.orglett.0c01080

Reference yield: 36.0%

: 459-57-4
4-fluorobenzaldehyde

: (E)-diethyl 3-methylbuta-1,3-dienylphosphonate

: 51795-72-3
diethyl 3-methylbut-2-enylphosphonate

: 71071-55-1
diethyl (3-methyl-3-butenyl)phosphonate

: (±)-diethyl (3S,5S,E)-5-hydroxy-3-methyl-5-(4-fluorophenyl)-pent-1-enyl phosphonate

Guidance literature:: (E)-diethyl 3-methylbuta-1,3-dienylphosphonate; With bis(acetylacetonate)nickel(II); In tetrahydrofuran; at 20 ℃; for 0.166667h; Inert atmosphere;

4-fluorobenzaldehyde; With triethyl borane; In tetrahydrofuran; at 20 ℃; for 36h; Inert atmosphere;
DOI:10.1021/acs.orglett.0c01080

Reference yield: 17.0%

: 123-08-0,65581-83-1
4-hydroxy-benzaldehyde

: (E)-diethyl 3-methylbuta-1,3-dienylphosphonate

: 51795-72-3
diethyl 3-methylbut-2-enylphosphonate

: 71071-55-1
diethyl (3-methyl-3-butenyl)phosphonate

: (±)-diethyl (3S,5S,E)-5-hydroxy-3-methyl-5-(4-hydroxyphenyl)-pent-1-enyl phosphonate

Guidance literature:: (E)-diethyl 3-methylbuta-1,3-dienylphosphonate; With bis(acetylacetonate)nickel(II); In tetrahydrofuran; at 20 ℃; for 0.166667h; Inert atmosphere;

4-hydroxy-benzaldehyde; With triethyl borane; In tetrahydrofuran; at 20 ℃; for 36h; Inert atmosphere;
DOI:10.1021/acs.orglett.0c01080