1-(tert-Butylsulfanyl)-4-fluorobenzene

Base Information

Chemical Name:1-(tert-Butylsulfanyl)-4-fluorobenzene
CAS No.:52323-92-9
Molecular Formula:C10H13FS
Molecular Weight:184.278
Hs Code.:
DSSTox Substance ID:DTXSID60495791
Nikkaji Number:J1.190.972H
Mol file:52323-92-9.mol

Synonyms:52323-92-9;1-(tert-Butylsulfanyl)-4-fluorobenzene;1-tert-butylsulfanyl-4-fluorobenzene;t-butyl 4-fluorophenyl sulfide;SCHEMBL7937564;DTXSID60495791

Suppliers and Price of 1-(tert-Butylsulfanyl)-4-fluorobenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-(tert-Butylsulfanyl)-4-fluorobenzene

Chemical Property:

Vapor Pressure:0.096mmHg at 25°C
XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:184.07219975
Heavy Atom Count:12
Complexity:131

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)SC1=CC=C(C=C1)F

Technology Process of 1-(tert-Butylsulfanyl)-4-fluorobenzene

There total 7 articles about 1-(tert-Butylsulfanyl)-4-fluorobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 371-42-6
4-Fluorothiophenol

: 691-64-5
di-tert-butyl oxalate

: 52323-92-9
tert-butyl-4-fluorophenyl sulfide

Guidance literature:: With copper(II) bis(trifluoromethanesulfonate); In 1,2-dichloro-ethane; at 40 ℃; for 12h; Sealed tube; Schlenk technique;
DOI:10.1021/acs.orglett.0c04206

Reference yield:

: 702-13-6
4-(isopropylthio)-1-fluorobenzene

: 74-88-4
methyl iodide

: 52323-92-9
tert-butyl-4-fluorophenyl sulfide

: 1-fluoro-4-isopropylsulfanyl-2-methyl-benzene

Guidance literature:: 4-(isopropylthio)-1-fluorobenzene; With n-butyllithium; In tetrahydrofuran; hexane; at -85 ℃; for 6h;

methyl iodide; In tetrahydrofuran; hexane; at 20 ℃; for 3h; Title compound not separated from byproducts;
DOI:10.1016/S0022-1139(99)00097-4

Reference yield:

: 352-33-0
1-Chloro-4-fluorobenzene

: 75-66-1
2-methylpropan-2-thiol

: 52323-92-9
tert-butyl-4-fluorophenyl sulfide

Guidance literature:: With [(C₆H₃(OP(i-Pr)2)2)RhHCl]; sodium t-butanolate; In toluene; at 110 ℃; for 24h; Sealed tube; Inert atmosphere;
DOI:10.1021/ja505576g