Decanedioic acid hydrogen 1-butyl ester

Base Information

• Chemical Name: Decanedioic acid hydrogen 1-butyl ester
• CAS No.: 5278-98-8
• Molecular Formula: C14H26O4
• Molecular Weight: 258.358
• Hs Code.: 2918990090
• Mol file: 5278-98-8.mol

Synonyms:

Chemical Property of Decanedioic acid hydrogen 1-butyl ester

Chemical Property:

• PSA: 63.60000
• LogP: 3.53510

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Decanedioic acid hydrogen 1-butyl ester

There total 3 articles about Decanedioic acid hydrogen 1-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

1,10-decanedioic acid (111-20-6,26776-29-4) + n-butyl formate (592-84-7) → Decanedioic acid monobutyl ester (5278-98-8) + dibutyl sebacate (109-43-3)

Guidance literature:

With Dowex 50W-X₂ (50-100 mesh); In octane; at 100 ℃; for 4.33333h;

DOI:10.1016/S0040-4039(96)01454-2

Reference yield:

1-bromo-butane (109-65-9) + 1,10-decanedioic acid (111-20-6,26776-29-4) → Decanedioic acid monobutyl ester (5278-98-8) + dibutyl sebacate (109-43-3)

Guidance literature:

With sodium hydroxide; Aliquat 336; In toluene; for 24h; Heating;

DOI:10.1016/0040-4020(89)80151-6

Reference yield:

dibutyl sebacate (109-43-3) → 1,10-decanedioic acid (111-20-6,26776-29-4) + Decanedioic acid monobutyl ester (5278-98-8)

Guidance literature:

With diethyl ether; water; sodium butanolate;

upstream raw materials:

dibutyl sebacate

1-bromo-butane

1,10-decanedioic acid

n-butyl formate

Downstream raw materials:

Decanedioic acid butyl ester 3,5-dimethoxy-2-[2-(4-methoxy-phenyl)-acetyl]-phenyl ester

Refernces

• 1、 Saitoh, Masahiko,Fujisaki, Shizuo,Ishii, Yasuhiro,Nishiguchi, Takeshi. "Convenient selective monoesterification of α, ω-dicarboxylic acids catalyzed by ion-exchange resins". . p. 6733 - 6736. Retrieved 2007/10/03.