Tetrahydropyranyl methacrylate

Base Information

• Chemical Name: Tetrahydropyranyl methacrylate
• CAS No.: 52858-59-0
• Molecular Formula: C9H14O3
• Molecular Weight: 170.208
• DSSTox Substance ID: DTXSID20452941
• Nikkaji Number: J425.387F
• Mol file: 52858-59-0.mol

Synonyms:52858-59-0;tetrahydropyranyl methacrylate;tetrahydro-2h-pyran-2-yl methacrylate;Oxan-2-yl 2-methylprop-2-enoate;2-Propenoic acid, 2-methyl-, tetrahydro-2H-pyran-2-yl ester;SCHEMBL219412;2-Tetrahvdropyranyl methacrylate;2-Tetrahydropyranyl Methacrylate;tetrahydropyran-2-yl methacrylate;DTXSID20452941;QHGUPRQTQITEPO-UHFFFAOYSA-N;AMY18682;AS-81005;CS-0111959;Methacrylic acid 1-oxacyclohexane-2-yl ester;E81390

Chemical Property of Tetrahydropyranyl methacrylate

Chemical Property:

• XLogP3: 1.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 170.094294304
• Heavy Atom Count: 12
• Complexity: 186

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OC1CCCCO1

Technology Process of Tetrahydropyranyl methacrylate

There total 2 articles about Tetrahydropyranyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

3,4-dihydro-2H-pyran (110-87-2) + poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) → 3,4,5,6-tetrahydropyran-2-yl methacrylate (52858-59-0)

Guidance literature:

With toluene-4-sulfonic acid; In dichloromethane; at 20 ℃; for 24h;

DOI:10.1021/ja904554m

Reference yield:

→ 3,4,5,6-tetrahydropyran-2-yl methacrylate (52858-59-0)

Guidance literature:

With 10H-phenothiazine; at 10 - 25 ℃; for 4h;

With pyridinium p-toluenesulfonate; at 25 ℃;

With sodium hydrogencarbonate; sodium sulfate; at 25 ℃; for 1h;

Reference yield:

3,4,5,6-tetrahydropyran-2-yl methacrylate (52858-59-0) → Naloxone (465-65-6)

Guidance literature:

upstream raw materials:

3,4-dihydro-2H-pyran

poly(methacrylic acid)

Downstream raw materials:

Naloxone

Refernces

• 1、 Georgiades, Savvas N.,Vamvakaki, Maria,Patrickios, Costas S.. "Synthesis and characterization of double-hydrophilic model networks based on cross-linked star polymers of poly(ethylene glycol) methacrylate and methacrylic acid". . p. 4903 - 4911. Retrieved 2002.
• 2、 -. "POSITIVE PHOTOSENSITIVE RESIN COMPOSITION, METHOD FOR FORMING CURED FILM, CURED FILM, ORGANIC EL DISPLAY DEVICE AND LIQUID CRYSTAL DISPLAY DEVICE". Paragraph 0400-0401; 0416. . Retrieved 2014/02/15.