1-Vinylbutyl chloride

Base Information

• Chemical Name: 1-Vinylbutyl chloride
• CAS No.: 53101-38-5
• Molecular Formula: C6H11Cl
• Molecular Weight: 118.60500
• Hs Code.: 2903299090
• Mol file: 53101-38-5.mol

Synonyms:3-Chlor-hex-1-en;3-Chlorhexen-1;1-Vinylbutyl chloride;3-chloro-hex-1-ene;n-propylallyl chloride;3-Chloro-1-hexene;cis-hexen-3-yl chloride;1-Hexene,3-chloro;

Chemical Property of 1-Vinylbutyl chloride

Chemical Property:

• Refractive Index: 1.4231 (estimate)
• Boiling Point: 134.88°C (estimate)
• PSA: 0.00000
• Density: 0.9241 (estimate)
• LogP: 2.57990

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Vinylbutyl chloride

There total 6 articles about 1-Vinylbutyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

1-hexene-3-ol (4798-44-1,67928-93-2) → 3-chloro-1-hexene (53101-38-5)

Guidance literature:

With hydrogenchloride; In dichloromethane; at 25 ℃; for 24h;

DOI:10.1002/jccs.200000053

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + (Z)-2-hexen-1-ol (928-94-9) → 3-chloro-1-hexene (53101-38-5) + 2-Hexenyl chloride (35911-16-1)

Guidance literature:

Reference yield:

→ 3-chloro-1-hexene (53101-38-5)

Guidance literature:

With pyridine; phosphorus trichloride; dextrorotatory 3-chloro-hexene-(1);

upstream raw materials:

pyridine

(3R)-1-hexen-3-ol

phosphorus trichloride

hydrogenchloride

Downstream raw materials:

ruthenium(IV)Cl(η5-pentamethylcyclopentadienyl)(Ph2(MeO)P)(η3-C3H7CHCHCH2) (PF6)

(E/Z)-2-hexenyltrimethylsilane

(-)-2-chloro-valeric acid

Refernces

• 1、 Khusnutdinov,Schadneva,Oshnyakova,Dzhemilev. "Addition of CCl4 to olefins catalyzed by chromium and ruthenium complexes: The influence of water as a nucleophilic additive". experimental part. p. 331 - 338. Retrieved 2010/06/16.