5-Methyl-5H-dibenzo[b,d]silole

Base Information

• Chemical Name: 5-Methyl-5H-dibenzo[b,d]silole
• CAS No.: 53268-89-6
• Molecular Formula: C13H12Si
• Molecular Weight: 196.324
• DSSTox Substance ID: DTXSID30788703
• Nikkaji Number: J2.136.784B
• Mol file: 53268-89-6.mol

Synonyms:5-Methyl-5H-dibenzo[b,d]silole;53268-89-6;1-hydro-1-methyldibenzosilole;5-Methyl-5H-dibenzosilole;5-methyl-5H-benzo[b][1]benzosilole;C13H12Si;9H-9-Methyl-9-sila-fluoren;DTXSID30788703;CS-0198505

Chemical Property of 5-Methyl-5H-dibenzo[b,d]silole

Chemical Property:

• PSA: 0.00000
• LogP: 1.63810
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 195.063001885
• Heavy Atom Count: 14
• Complexity: 191

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si]1C2=CC=CC=C2C3=CC=CC=C31

Technology Process of 5-Methyl-5H-dibenzo[b,d]silole

There total 4 articles about 5-Methyl-5H-dibenzo[b,d]silole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + 1-methyl-1-(trimethylsilyl)dibenzosilole (80073-04-7) → 1-hydro-1-methyldibenzosilole (53268-89-6) + Trimethylmethoxysilane (1825-61-2)

Guidance literature:

for 0.25h; Irradiation;

DOI:10.1016/0022-328X(84)85134-7

Reference yield:

1-methyl-1-(trimethylsilyl)dibenzosilole (80073-04-7) → 1-hydro-1-methyldibenzosilole (53268-89-6) + Trimethylmethoxysilane (1825-61-2)

Guidance literature:

With methanol; for 0.25h; Irradiation;

DOI:10.1016/0022-328X(84)85134-7

Reference yield:

bis(o-chlorophenyl)methylsilane (87938-58-7) → 1-hydro-1-methyldibenzosilole (53268-89-6) + methyldiphenylsilane (776-76-1) + 9,9,10-trimethyl-9,10-dihydro-9,10-disilaanthracene (87938-52-1)

Guidance literature:

With magnesium; dimethylsilicon dichloride; Yield given. Multistep reaction. Title compound not separated from byproducts; 1.) THF, reflux, 48 h, 2.) THF;

DOI:10.1016/0022-328X(84)85185-2

upstream raw materials:

dimethylsilicon dichloride

bis(o-chlorophenyl)methylsilane

methanol

1-methyl-1-(trimethylsilyl)dibenzosilole

Downstream raw materials:

2,5-Diphenyl-thiophene

bis-(1-methyldibenzosilolyl)sulfide