(Z)-4-Octen-1-ol

Base Information

• Chemical Name: (Z)-4-Octen-1-ol
• CAS No.: 54393-36-1
• Molecular Formula: C8H16O
• Molecular Weight: 128.214
• UNII: 2XT1281K6U
• Nikkaji Number: J1.898.200E
• Wikidata: Q27255781
• Mol file: 54393-36-1.mol

Synonyms:(Z)-4-Octen-1-ol;CIS-4-OCTENOL;cis-4-Octenol [FHFI];4-Octen-1-ol, (Z)-;FEMA No. 4354;4-Octen-1-ol, (4Z)-;54393-36-1;2XT1281K6U;UNII-2XT1281K6U;(Z)-4-Octene-1-ol;(Z)-oct-4-en-1-ol;z-4-octenol;(4Z)-4-octen-1-ol;SCHEMBL1243771;4-OCTEN-1-OL, CIS-;OZQBPZSICOOLGU-PLNGDYQASA-N;Q27255781;3-(3-Methylbenzoyl)[1,2,4]triazolo[1,5-a]pyridine-2(3H)-thione

Chemical Property of (Z)-4-Octen-1-ol

Chemical Property:

• XLogP3: 2.2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 128.120115130
• Heavy Atom Count: 9
• Complexity: 67

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC=CCCCO
• Isomeric SMILES: CCC/C=C\CCCO

Technology Process of (Z)-4-Octen-1-ol

There total 1 articles about (Z)-4-Octen-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,4-dihydro-2H-pyran (110-87-2) + n-propylmagnesium bromide (927-77-5) → n-Pent-4-enyl alcohol (821-09-0) + (Z)-4-octene-1-ol (54393-36-1)

Guidance literature:

With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); In benzene; at 70 ℃; for 20h;

DOI:10.1021/jo00205a042

Reference yield: 82.0%

(Z)-4-octene-1-ol (54393-36-1) → (Z)-oct-4-enal (39924-26-0)

Guidance literature:

With pyridinium chlorochromate; In dichloromethane; for 2h;

DOI:10.1002/jlac.198119810920

Reference yield:

(Z)-4-octene-1-ol (54393-36-1) → (Z)-8-dodecen-1-yl acetate (28079-04-1)

Guidance literature:

Multi-step reaction with 3 steps

1: 90 percent / triphenylphosphine, bromine / CCl₄ / 1) 15 deg C, 1 h; 2) room temp., 15 h.

2: 1) cuprous iodide, 2,2'-bipyridyl 2) Mg / 1) abs. THF, 20 deg C, 0.5 h; 2) abs. THF, 2 h at 2 deg C and 15 h at room temp.

3: 1) p-toluenesulfonic acid, water; 2) pyridine / 1) MeOH, room temp., 15 h; 2) room temp., 24 h.

With pyridine; [2,2]bipyridinyl; copper(l) iodide; water; bromine; toluene-4-sulfonic acid; magnesium; triphenylphosphine; In tetrachloromethane;

upstream raw materials:

3,4-dihydro-2H-pyran

n-propylmagnesium bromide

Downstream raw materials:

(Z)-oct-4-enal

(Z)-8-dodecen-1-yl acetate

<(Z)-4-Octenyl>-triphenylphosphonium-bromid