2,4-Hexadienoic acid, 5-methyl-, ethyl ester, (2E)-

Base Information

Chemical Name:2,4-Hexadienoic acid, 5-methyl-, ethyl ester, (2E)-
CAS No.:54542-32-4
Molecular Formula:C9H14O2
Molecular Weight:154.209
Hs Code.:

Synonyms:5-methyl-hexa-2t,4-dienoic acid ethyl ester;ethyl (E)-5-methylhexa-2,4-dienoate;ethyl 2-trans-5-methyl-2,4-hexadienoate;5-Methyl-hexa-2t,4-diensaeure-aethylester;(2E,4E)-ethyl 2-methylhexa-2,4-dienoate;2,4-Hexadienoic acid,5-methyl-,ethyl ester,(2E);ethyl (E)-5-methyl-2,4-hexadienoate;

Suppliers and Price of 2,4-Hexadienoic acid, 5-methyl-, ethyl ester, (2E)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 2,4-Hexadienoic acid, 5-methyl-, ethyl ester, (2E)-

Chemical Property:

PSA：26.30000
LogP:2.07190

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2,4-Hexadienoic acid, 5-methyl-, ethyl ester, (2E)-

There total 2 articles about 2,4-Hexadienoic acid, 5-methyl-, ethyl ester, (2E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2-methylprop-1-enyl(triphenyl)bismuthonium tetrafluoroborate

: 140-88-5,9003-32-1
ethyl acrylate

: 92-52-4,1594-86-1
biphenyl

: 54542-32-4
ethyl (E)-5-methyl-2,4-hexadienoate

: 768-49-0
(2-methyl-1-propenyl)-benzene

: 4192-77-2
ethyl cinnamate

Guidance literature:: With sodium hydrogencarbonate; palladium diacetate; In dichloromethane; N,N-dimethyl-formamide; Product distribution; also Et₃N, Pd(PPh₃)4;
DOI:10.1039/p19960001971

Reference yield:

: 66680-86-2
isobutenyltributyltin

: 140-88-5,9003-32-1
ethyl acrylate

: 54542-32-4
ethyl (E)-5-methyl-2,4-hexadienoate

: 4192-77-2
ethyl cinnamate

Guidance literature:: With palladium diacetate; boron trifluoride diethyl etherate; triphenylbismuth(V) difluoride; Yield given. Multistep reaction. Yields of byproduct given; 1.) CH₂Cl₂, r.t., 12 h, 2.) DMF, r.t., 1.5 h;
DOI:10.1039/p19960001971

Reference yield: 65.0%

: 594-16-1
2,2-dibromopropane

: 54542-32-4
ethyl (E)-5-methyl-2,4-hexadienoate

: 97-41-6,1802-02-4,7377-84-6,15543-65-4,16642-27-6,34909-55-2,41641-25-2,41641-26-3,41641-27-4
ethyl trans-(+/-)-chrysanthemate

Guidance literature:: ethyl (E)-5-methyl-2,4-hexadienoate; With C₂₉H₃₅Br₂CoN₃; zinc dibromide; zinc; In tetrahydrofuran; at 22 ℃; for 0.25h; Inert atmosphere; Glovebox;

2,2-dibromopropane; In tetrahydrofuran; at 22 ℃; for 24h; regioselective reaction; Inert atmosphere; Glovebox;
DOI:10.1002/anie.201807542