2-Methylpropene-1-tributylstannane

Base Information

Chemical Name:2-Methylpropene-1-tributylstannane
CAS No.:66680-86-2
Molecular Formula:C16H34Sn
Molecular Weight:345.156
Hs Code.:2931900090
European Community (EC) Number:846-307-0
DSSTox Substance ID:DTXSID00471938
Mol file:66680-86-2.mol

Synonyms:2-Methylpropene-1-tributylstannane;66680-86-2;Tributyl(2-methylprop-1-enyl)stannane;2-Methyl-1-(tributylstannyl)prop-1-ene;MFCD09750019;isobutenyltri-n-butyltin;tributyl(2-methylprop-1-en-1-yl)stannane;2-methyl-propenyl tributyltin;DTXSID00471938;LWNCDBSQZPDFOG-UHFFFAOYSA-N;(2-Methyl-1-propenyl)tributylstannane;AKOS015843051;SY283869;FT-0685411;2-methylpropene-1-tributylstannane, AldrichCPR;A50110;J-510087

Suppliers and Price of 2-Methylpropene-1-tributylstannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

SynQuest Laboratories
2-Methyl-1-(tributylstannyl)prop-1-ene
1 g
$ 288.00

SynQuest Laboratories
2-Methyl-1-(tributylstannyl)prop-1-ene
5 g
$ 704.00

Matrix Scientific
2-Methylpropene-1-tributylstannane 96%
5g
$ 588.00

Matrix Scientific
2-Methylpropene-1-tributylstannane 96%
1g
$ 242.00

Matrix Scientific
2-Methylpropene-1-tributylstannane 96%
25g
$ 1764.00

American Custom Chemicals Corporation
2-METHYL-1-(TRIBUTYLSTANNYL)PROP-1-ENE 95.00%
1G
$ 759.41

AK Scientific
2-Methylpropene-1-tributylstannane
1g
$ 211.00

Total 11 raw suppliers

Chemical Property of 2-Methylpropene-1-tributylstannane

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Boiling Point:330.124oC at 760 mmHg
Flash Point:157.636oC
PSA：0.00000
LogP:6.34090
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:10
Exact Mass:346.168254
Heavy Atom Count:17
Complexity:180

Purity/Quality:

98%min ^*data from raw suppliers

2-Methyl-1-(tributylstannyl)prop-1-ene ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:T

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC[Sn](CCCC)(CCCC)C=C(C)C
Uses 2-Methylpropene-1-tributylstannane is used in the preparation of serrulatane and amphilectane diterpenes.

Technology Process of 2-Methylpropene-1-tributylstannane

There total 6 articles about 2-Methylpropene-1-tributylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 3017-69-4
2-methyl-1-propenylbromide

: tributyltin iodide

: 66680-86-2
isobutenyltributyltin

Guidance literature:: With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 - 20 ℃; for 23h; Inert atmosphere;
DOI:10.1021/jacs.8b03549

Reference yield: 58.0%

: 3017-69-4
2-methyl-1-propenylbromide

: 1461-22-9
tributyltin chloride

: 66680-86-2
isobutenyltributyltin

Guidance literature:: 2-methyl-1-propenylbromide; With iodine; magnesium; In tetrahydrofuran; for 0.05h; Heating / reflux;

With methyl iodide; In tetrahydrofuran; at 25 ℃; for 2.5h; Heating / reflux;

tributyltin chloride; In tetrahydrofuran; for 19h; Heating / reflux;

Reference yield: 46.0%

: 3017-69-4
2-methyl-1-propenylbromide

: 1461-22-9
tributyltin chloride

: 7439-95-4
magnesium

: 106-93-4
ethylene dibromide

: 66680-86-2
isobutenyltributyltin

Guidance literature:: In tetrahydrofuran; addn. of vinyl bromide and ethylene dibromide to Mg in THF (N2 atmosphere), addn. of further vinyl bromide in THF during 1 h at reflux, decantation, addn. of Sn-compd., refluxing (1 h), cooling room temp.); evapn., partition (Et2O-H2O), washing etheral phase (H2O), drying, evapn., distn.; elem. anal.;