ETHYL 5-METHYLHEXANOATE

Base Information

• Chemical Name: ETHYL 5-METHYLHEXANOATE
• CAS No.: 10236-10-9
• Molecular Formula: C9H18 O2
• Molecular Weight: 158.241
• Hs Code.: 2915900090
• Mol file: 10236-10-9.mol

Synonyms:5-Methylhexanoicacid ethyl ester; Ethyl 5-methylhexanoate; NSC 33948

Chemical Property of ETHYL 5-METHYLHEXANOATE

Chemical Property:

• Vapor Pressure: 1.09mmHg at 25°C
• Boiling Point: 176.5°Cat760mmHg
• Flash Point: 59.4°C
• PSA: 26.30000
• Density: 0.874g/cm³
• LogP: 2.37580

Purity/Quality:

98%,99%, ^*data from raw suppliers

5-Methylhexanoicacidethylester ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ETHYL 5-METHYLHEXANOATE

There total 13 articles about ETHYL 5-METHYLHEXANOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

ethyl 5-methyl-4-hexenoate (42272-93-5) → ethyl isoamylacetate (10236-10-9)

Guidance literature:

With tert.-butylhydroperoxide; bis(2,2,6,6-tetramethyl-3,5-heptanedionato)cobalt(II); phenylsilane; In decane; 1,2-dichloro-ethane; isopropyl alcohol; chemoselective reaction; Inert atmosphere;

DOI:10.1021/ja412342g

Reference yield: 17.0%

diazoacetic acid ethyl ester (623-73-4) + methylbutane (78-78-4) → 4-methyl-hexanoic acid ethyl ester (1561-10-0) + ethyl isoamylacetate (10236-10-9) + 3,3-dimethyl-valeric acid ethyl ester (80246-75-9) + ethyl 3,4-dimethylpentanoate (6570-83-8) + C11H20O4 + C11H20O4

Guidance literature:

With C₁₅HBBr₃F₁₈N₆^(1-)*Ag⁽¹⁺⁾*C₄H₈O; In water; at 20 ℃; regioselective reaction;

DOI:10.1021/acscatal.6b03669

Reference yield:

3-methylbutyric acid (503-74-2) + butanedioic acid, monoethyl ester (1070-34-4) → 2,5-dimethylhexane (592-13-2) + ethyl isoamylacetate (10236-10-9) + diethyl adipate (141-28-6)

Guidance literature:

With triethylamine; In methanol; water; at 0 ℃; Concentration; Solvent; Reagent/catalyst; Electrochemical reaction;

DOI:10.1039/c8gc03745k

upstream raw materials:

ethanol

5-methylhexanoic acid

ethyl (E)-5-methyl-2,4-hexadienoate

isobutene

Downstream raw materials:

2,6-dimethylheptan-2-ol

5-methyl-1-hexanol

diethyl isopentylmalonate

diethyl ethylisopentylmalonate