Phenol, 2-(iminophenylmethyl)-

Base Information

• Chemical Name: Phenol, 2-(iminophenylmethyl)-
• CAS No.: 54758-71-3
• Molecular Formula: C13H11NO
• Molecular Weight: 197.236
• Mol file: 54758-71-3.mol

Synonyms:o-Hydroxibenzophenonimin;2-hydroxy-benzophenone-imine;Phenol,2-(iminophenylmethyl);2-Hydroxy-benzophenon-imin;2-(imino(phenyl)methyl)phenol;2-Hydroxy-diphenylketoimin;o,hydroxybenzophenone imine;2-benzenecarboximidoylphenol;

Chemical Property of Phenol, 2-(iminophenylmethyl)-

Chemical Property:

• PSA: 43.09000
• LogP: 2.75180

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phenol, 2-(iminophenylmethyl)-

There total 2 articles about Phenol, 2-(iminophenylmethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2-Hydroxybenzophenone (117-99-7) → 2-(imino(phenyl)methyl)phenol (54758-71-3)

Guidance literature:

With ammonia; In methanol; at 20 ℃; for 16h; Cooling with ice;

DOI:10.1002/chem.201101694

Reference yield:

salicylonitrile (611-20-1) + phenylmagnesium bromide → 2-(imino(phenyl)methyl)phenol (54758-71-3)

Guidance literature:

With diethyl ether;

DOI:10.1021/ja01154a102

Reference yield: 98.0%

2-(imino(phenyl)methyl)phenol (54758-71-3) + (E)-1-fluoro-2-(2-nitrovinyl)benzene (192818-72-7) → (R,E)-2-(((1-(2-fluorophenyl)-2-nitroethyl)imino)(phenyl)methyl)phenol

Guidance literature:

With C₂₉H₂₈F₆N₄OS; In dichloromethane; at 20 ℃; for 12h; enantioselective reaction;

DOI:10.1002/adsc.202100635

upstream raw materials:

salicylonitrile

2-Hydroxybenzophenone

Downstream raw materials:

2-oxo-4-phenyl-2H-chromene-3-carbonitrile

4-phenylcoumarin

(S)-2-(amino(phenyl)methyl)phenol

rac-2-[amino(phenyl)methyl]phenol