dimethyl (1R,2S)-4,5-dimethyl-4-cyclohexene-1,2-dicarboxylate

Base Information

Chemical Name:dimethyl (1R,2S)-4,5-dimethyl-4-cyclohexene-1,2-dicarboxylate
CAS No.:55264-91-0
Molecular Formula:C12H18O4
Molecular Weight:226.26900
Hs Code.:2917200090
DSSTox Substance ID:DTXSID20377625
Wikidata:Q82166907
Mol file:55264-91-0.mol

Synonyms:55264-91-0;dimethyl (1R,2S)-4,5-dimethyl-4-cyclohexene-1,2-dicarboxylate;1,2-dimethyl (1R,2S)-4,5-dimethylcyclohex-4-ene-1,2-dicarboxylate;dimethyl (1S,2R)-4,5-dimethylcyclohex-4-ene-1,2-dicarboxylate;11P-149;DTXSID20377625;MFCD02571655;AKOS005078811;1,2-dimethyl(1R,2S)-4,5-dimethylcyclohex-4-ene-1,2-dicarboxylate

Suppliers and Price of dimethyl (1R,2S)-4,5-dimethyl-4-cyclohexene-1,2-dicarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Matrix Scientific
Dimethyl (1R,2S)-4,5-dimethyl-4-cyclohexene-1,2-dicarboxylate
10mg
$ 146.00

Matrix Scientific
Dimethyl (1R,2S)-4,5-dimethyl-4-cyclohexene-1,2-dicarboxylate
5mg
$ 105.00

Matrix Scientific
Dimethyl (1R,2S)-4,5-dimethyl-4-cyclohexene-1,2-dicarboxylate
1mg
$ 90.00

American Custom Chemicals Corporation
DIMETHYL(1R,2S)-4,5-DIMETHYL-4-CYCLOHEXENE-1,2-DICARBOXYLATE 95.00%
10MG
$ 707.14

American Custom Chemicals Corporation
DIMETHYL(1R,2S)-4,5-DIMETHYL-4-CYCLOHEXENE-1,2-DICARBOXYLATE 95.00%
5MG
$ 687.35

American Custom Chemicals Corporation
DIMETHYL(1R,2S)-4,5-DIMETHYL-4-CYCLOHEXENE-1,2-DICARBOXYLATE 95.00%
1MG
$ 647.61

Total 3 raw suppliers

Chemical Property of dimethyl (1R,2S)-4,5-dimethyl-4-cyclohexene-1,2-dicarboxylate

Chemical Property:

PSA：52.60000
LogP:1.69500
XLogP3:0.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:226.12050905
Heavy Atom Count:16
Complexity:298

Purity/Quality:

99% ^*data from raw suppliers

Dimethyl (1R,2S)-4,5-dimethyl-4-cyclohexene-1,2-dicarboxylate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=C(CC(C(C1)C(=O)OC)C(=O)OC)C
Isomeric SMILES:CC1=C(C[C@@H]([C@@H](C1)C(=O)OC)C(=O)OC)C

Technology Process of dimethyl (1R,2S)-4,5-dimethyl-4-cyclohexene-1,2-dicarboxylate

There total 6 articles about dimethyl (1R,2S)-4,5-dimethyl-4-cyclohexene-1,2-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 513-81-5
2,3-dimethyl-buta-1,3-diene

: 624-49-7
dimethylfumarate

: 6096-53-3,22230-97-3,55264-91-0,137492-78-5,1881275-59-7
dimethyl trans-1,2-dimethylcyclohexene-4,5-dicarboxylate

Guidance literature:: In toluene; at 50 ℃; for 24h; Inert atmosphere;
DOI:10.1039/c7gc03819d

Reference yield: 10.0%

: 624-48-6
dimethyl cis-but-2-ene-1,4-dioate

: 513-81-5
2,3-dimethyl-buta-1,3-diene

: 55264-91-0,1881275-59-7
dimethyl 1,2-dimethylcyclohexene-4,5-cis-dicarboxylate

Guidance literature:: In toluene; at 50 ℃; for 24h; Inert atmosphere;
DOI:10.1039/c7gc03819d

Reference yield:

: 513-81-5
2,3-dimethyl-buta-1,3-diene

: 23055-10-9
1,4-dimethyl but-2-enedioate

: 137492-78-5,1881275-59-7
dimethyl (4S,5S)-1,2-dimethylcyclohexene-4,5-dicarboxylate

: 6096-53-3,22230-97-3,55264-91-0,137492-78-5,1881275-59-7
dimethyl (4R,5R)-1,2-dimethylcyclohexene-4,5-dicarboxylate

Guidance literature:: With C₁₆H₁₆Cl₂O₄Ti; In diethyl ether; dichloromethane; at 30 ℃; for 4h; Solvent; Overall yield = 84 %; enantioselective reaction; Catalytic behavior; Inert atmosphere;
DOI:10.13005/ojc/320217