1-Methoxy-4-{[(prop-1-en-2-yl)oxy]methyl}benzene

Base Information

• Chemical Name: 1-Methoxy-4-{[(prop-1-en-2-yl)oxy]methyl}benzene
• CAS No.: 55831-55-5
• Molecular Formula: C11H14O2
• Molecular Weight: 178.231
• DSSTox Substance ID: DTXSID10573937
• Nikkaji Number: J1.815.997J
• Wikidata: Q82462792
• Mol file: 55831-55-5.mol

Synonyms:55831-55-5;1-Methoxy-4-{[(prop-1-en-2-yl)oxy]methyl}benzene;SCHEMBL6693729;DTXSID10573937

Chemical Property of 1-Methoxy-4-{[(prop-1-en-2-yl)oxy]methyl}benzene

Chemical Property:

• XLogP3: 2.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 178.099379685
• Heavy Atom Count: 13
• Complexity: 158

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)OCC1=CC=C(C=C1)OC

Technology Process of 1-Methoxy-4-{[(prop-1-en-2-yl)oxy]methyl}benzene

There total 5 articles about 1-Methoxy-4-{[(prop-1-en-2-yl)oxy]methyl}benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

Isopropenyl acetate (108-22-5) + 4-Methoxybenzyl alcohol (105-13-5) → 1-isoprenyloxymethyl-4-methoxybenzene (55831-55-5)

Guidance literature:

With bis(1,5-cyclooctadiene)diiridium(I) dichloride; sodium carbonate; In toluene; at 100 ℃; for 3h; Inert atmosphere;

DOI:10.1016/j.tet.2012.02.025

Reference yield: 38.0%

p-methoxybenzyl acetate (104-21-2) + 1,1-dibromomethane (74-95-3) → 1-isoprenyloxymethyl-4-methoxybenzene (55831-55-5)

Guidance literature:

With N,N,N,N,-tetramethylethylenediamine; zinc; titanium tetrachloride; In tetrahydrofuran; dichloromethane;

DOI:10.1002/adsc.200303059

Reference yield:

p-methoxybenzyl acetate (104-21-2) → 1-isoprenyloxymethyl-4-methoxybenzene (55831-55-5)

Guidance literature:

With pyridine; In tetrahydrofuran; at -45 - 20 ℃;

DOI:10.1039/b003277h

upstream raw materials:

p-methoxybenzyl acetate

1,1-dibromomethane

4-Methoxybenzyl alcohol

Isopropenyl acetate

Downstream raw materials:

4-(4-methoxy-phenyl)-butan-2-ol

4-(4-methoxyphenyl)-2-butanone

C₁₉H₂₆O₂Si