O-(2-Methylpropyl)hydroxylamine

Base Information

• Chemical Name: O-(2-Methylpropyl)hydroxylamine
• CAS No.: 5618-62-2
• Molecular Formula: C4H11NO
• Molecular Weight: 89.1374
• Mol file: 5618-62-2.mol

Synonyms:O-isobutyl-hydroxylamine;Isobutoxyamin;O-Isobutyl-hydroxylamin;isobutoxy amine;Hydroxylamine,O-isobutyl;TPC-A019;

Chemical Property of O-(2-Methylpropyl)hydroxylamine

Chemical Property:

• Vapor Pressure: 16.7mmHg at 25°C
• Boiling Point: 118.4oC at 760 mmHg
• PKA: 4.71±0.70(Predicted)
• Flash Point: 24.4oC
• PSA: 35.25000
• Density: 0.849g/cm3
• LogP: 1.23300

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of O-(2-Methylpropyl)hydroxylamine

There total 6 articles about O-(2-Methylpropyl)hydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

O-1-(2-methyl)propyl-N-hydroxyphthalimide (52026-51-4) → O-isobutylhydroxylamine (5618-62-2)

Guidance literature:

With methylhydrazine; In dichloromethane; at 20 ℃;

DOI:10.1016/j.bmcl.2008.10.054

Reference yield:

Isobutyl iodide (513-38-2) + ethyl N-hydroxylcarbamate (589-41-3) → O-isobutylhydroxylamine (5618-62-2)

Guidance literature:

With potassium hydroxide; Erhitzen des Reaktionsprodukts mit wss.Kalilauge;

DOI:10.1021/ja01155a540

Reference yield:

N-isobutoxy-acetimidic acid ethyl ester (18498-63-0) → O-isobutylhydroxylamine (5618-62-2)

Guidance literature:

With hydrogenchloride; In diethyl ether;

DOI:10.1007/BF00906825

upstream raw materials:

Isobutyl iodide

ethyl N-hydroxylcarbamate

sodium isobutoxide

N-isobutoxy-acetimidic acid ethyl ester

Downstream raw materials:

5-bromo-3,4-difluoro-2-(4-iodo-2-methyl-phenylamino)-N-isobutoxy-benzamide

O-isobutylhydroxylamine hydrochloride

Refernces

• 1、 Huang, Jia-Xing,Jia, Yue-Mei,Liang, Xiao-Mei,Zhu, Wei-Juan,Zhang, Jian-Jun,Dong, Yan-Hong,Yuan, Hui-Zu,Qi, Shu-Hua,Wu, Jin-Ping,Chen, Fu-Heng,Wang, Dao-Quan. "Synthesis and fungicidal activity of macrolactams and macrolactones with an oxime ether side chain". experimental part. p. 10857 - 10863. Retrieved 2009/11/30.