Benzaldehyde, 3-nitro-, [(3-nitrophenyl)methylene]hydrazone

Base Information

• Chemical Name: Benzaldehyde, 3-nitro-, [(3-nitrophenyl)methylene]hydrazone
• CAS No.: 1567-91-5
• Molecular Formula: C₁₄H₁₀N₄O₄
• Molecular Weight: 298.258
• NSC Number: 80713
• DSSTox Substance ID: DTXSID30420838
• Mol file: 1567-91-5.mol

Synonyms:NSC80713;1567-91-5;(E)-1-(3-Nitrophenyl)-N-[(Z)-(3-nitrophenyl)methylideneamino]methanimine;Benzaldehyde, 3-nitro-, [(3-nitrophenyl)methylene]hydrazone;DTXSID30420838;NSC-80713;3-nitrobenzaldehyde (3-nitrobenzylidene)hydrazone;Benzaldehyde, [(3-nitrophenyl)methylene]hydrazone

Chemical Property of Benzaldehyde, 3-nitro-, [(3-nitrophenyl)methylene]hydrazone

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 457°Cat760mmHg
• Flash Point: 230.2°C
• Density: 1.34g/cm³
• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 298.07020481
• Heavy Atom Count: 22
• Complexity: 413

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC(=C1)[N+](=O)[O-])C=NN=CC2=CC(=CC=C2)[N+](=O)[O-]
• Isomeric SMILES: C1=CC(=CC(=C1)[N+](=O)[O-])/C=N/N=C\C2=CC(=CC=C2)[N+](=O)[O-]

Technology Process of Benzaldehyde, 3-nitro-, [(3-nitrophenyl)methylene]hydrazone

There total 20 articles about Benzaldehyde, 3-nitro-, [(3-nitrophenyl)methylene]hydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

3-nitro-benzaldehyde (99-61-6) → 3-nitrobenzaldehyde N-[-(3-nitrophenyl)methylidene]hydrazone (41097-40-9,1567-91-5)

Guidance literature:

With carbazic acid; at 60 ℃; for 5h; Neat (no solvent);

DOI:10.1021/ol202593g

Reference yield: 85.0%

N'-(3-nitrobenzylidene)-4-methylbenzenesulfonohydrazide (3748-99-0) → 3-nitrobenzaldehyde N-[-(3-nitrophenyl)methylidene]hydrazone (41097-40-9,1567-91-5)

Guidance literature:

With caesium carbonate; In acetonitrile; at 100 ℃; for 6h; Sealed tube;

DOI:10.1007/s11164-016-2688-3

Reference yield: 13.0%

Thiram (137-26-8,93196-73-7) + 3-nitrobenzaldehyde hydrazone (3718-22-7) → 3-nitrobenzaldehyde N-[-(3-nitrophenyl)methylidene]hydrazone (41097-40-9,1567-91-5) + 4,4-dimethylthiosemicarbazide (6926-58-5) + 5-dimethylamino-1,3,4-thiadiazole-2-thiol (2810-66-4) + N,N-dimethyl-m-nitrothiobenzamide

Guidance literature:

In 1,4-dioxane; at 80 ℃; for 1h; Further Variations:; Temperatures; reagent ratio; Product distribution;

DOI:10.1007/BF02494686

upstream raw materials:

3-nitrobenzaldehyde hydrazone

3-nitro-benzaldehyde

N-(3-Nitro-benzyliden)-4-rhodan-anilin

ethanol

Downstream raw materials:

3-nitro-N'-(3-nitro-benzylidene)-benzohydrazonoyl chloride

m-aminobenzaldehyde

3-nitro-benzaldehyde semicarbazone

3-nitro-benzaldehyde