Ethenamine, 2-phenyl-

Base Information

• Chemical Name: Ethenamine, 2-phenyl-
• CAS No.: 5694-20-2
• Molecular Formula: C8H9N
• Molecular Weight: 119.166
• DSSTox Substance ID: DTXSID00276445
• Mol file: 5694-20-2.mol

Synonyms:aminostyrene;Ethenamine, 2-phenyl-;(2-phenylvinyl)amine;5694-20-2;N-(benzylidene)methylamine;DTXSID00276445;UWRZIZXBOLBCON-UHFFFAOYSA-N

Chemical Property of Ethenamine, 2-phenyl-

Chemical Property:

• XLogP3: 1.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 119.073499291
• Heavy Atom Count: 9
• Complexity: 90.7

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C=CN

Technology Process of Ethenamine, 2-phenyl-

There total 6 articles about Ethenamine, 2-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(2-nitroethenyl)benzene (102-96-5) → N-benzylidenemethylamine (5694-20-2)

Guidance literature:

With sodium tetrahydroborate; In water; at 45 ℃; for 0.25h;

DOI:10.1002/aoc.3258

Reference yield: 88.0%

β-azidostyrene (16722-99-9) → N-benzylidenemethylamine (5694-20-2)

Guidance literature:

With Ba(BH₂S₃)2; In tetrahydrofuran; at 20 ℃;

DOI:10.1080/10426500008076533

Reference yield:

3-phenyl-propenal (104-55-2) → N-benzylidenemethylamine (5694-20-2)

Guidance literature:

With glucose dehydrogenase; L-alanin; D-glucose; L-alanine dehydrogenase; amine transaminase; ammonium chloride; sodium hydroxide; In dimethyl sulfoxide; at 37 ℃; for 22h; pH=8.2; Darkness; Enzymatic reaction;

DOI:10.1002/adsc.201301148

upstream raw materials:

1,3,5-Tribenzyl-1,3,5-triazacyclohexane

sodium ethanolate

N-benzyl-N-methyl-p-toluenesulfonamide

(2-nitroethenyl)benzene

Downstream raw materials:

N-(4-vinylphenyl)-2-chloroacetamide

2,2,2-trifluoro-N-(2-phenylethenyl)acetamide

(R,S)-N,N'-dimethyl-1,2-diphenylethylenediamine

N,5-dimethyl-2,4-dinitroaniline

Refernces

• 1、 -. "ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES". Paragraph 0146-0147. . Retrieved 2019/05/18.
• 2、 Sun, Shuai,Quan, Zhengjun,Wang, Xicun. "Selective reduction of nitro-compounds to primary amines by nickel-catalyzed hydrosilylative reduction". . p. 84574 - 84577. Retrieved 2015/10/28.